Aquabis(3,5-dimethyl-1H-pyrazole-kappa N-2)(malonato-kappa O-2,O ')copper(II) dihydrate
(2001) In Acta Crystallographica. Section C: Crystal Structure Communications 57. p.1385-1387- Abstract
- In the neutral title complex, [Cu(C3H2O4)(C5H8N2)(2-)(H2O)]. 2H(2)O or [Cu(mal)(dmp)(2)(H2O)]. 2H(2)O (mal is malonate and dmp is 3,5-dimethyl-1H-pyrazole), the Cu-II ion, in a slightly distorted square-pyramidal geometry, is coordinated by two O atoms of the bidentate malonate, the O atom of the water ligand and two N atoms from the two 3,5-dimethylpyrazole ligands. The mean Cu-N bond length is 2.007 (6) Angstrom, longer than the Cu-O-mal bonds [1.950 (5) Angstrom]. The apical position is occupied by a relatively strongly coordinated water molecule [Cu-O-water 2.288 (5) Angstrom]. The crystal structure is characterized by the layer motif of a hydrogen-bonded network.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3915885
- author
- Xiong, Y ; Tong, ML ; An, TC and Karlsson, Hans LU
- organization
- publishing date
- 2001
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta Crystallographica. Section C: Crystal Structure Communications
- volume
- 57
- pages
- 1385 - 1387
- publisher
- International Union of Crystallography
- external identifiers
-
- wos:000172548200008
- scopus:0035683977
- ISSN
- 0108-2701
- DOI
- 10.1107/S0108270101015116
- language
- English
- LU publication?
- yes
- id
- 6d0ac6e2-d2b5-456f-a357-dd40d1602d54 (old id 3915885)
- date added to LUP
- 2016-04-01 16:00:33
- date last changed
- 2023-09-04 10:46:46
@article{6d0ac6e2-d2b5-456f-a357-dd40d1602d54, abstract = {{In the neutral title complex, [Cu(C3H2O4)(C5H8N2)(2-)(H2O)]. 2H(2)O or [Cu(mal)(dmp)(2)(H2O)]. 2H(2)O (mal is malonate and dmp is 3,5-dimethyl-1H-pyrazole), the Cu-II ion, in a slightly distorted square-pyramidal geometry, is coordinated by two O atoms of the bidentate malonate, the O atom of the water ligand and two N atoms from the two 3,5-dimethylpyrazole ligands. The mean Cu-N bond length is 2.007 (6) Angstrom, longer than the Cu-O-mal bonds [1.950 (5) Angstrom]. The apical position is occupied by a relatively strongly coordinated water molecule [Cu-O-water 2.288 (5) Angstrom]. The crystal structure is characterized by the layer motif of a hydrogen-bonded network.}}, author = {{Xiong, Y and Tong, ML and An, TC and Karlsson, Hans}}, issn = {{0108-2701}}, language = {{eng}}, pages = {{1385--1387}}, publisher = {{International Union of Crystallography}}, series = {{Acta Crystallographica. Section C: Crystal Structure Communications}}, title = {{Aquabis(3,5-dimethyl-1H-pyrazole-kappa N-2)(malonato-kappa O-2,O ')copper(II) dihydrate}}, url = {{http://dx.doi.org/10.1107/S0108270101015116}}, doi = {{10.1107/S0108270101015116}}, volume = {{57}}, year = {{2001}}, }