New Methods for Synthesis of Platinum(II) Dimethyl Sulfide Complexes
(1994) In Inorganica Chimica Acta 219(1-2). p.155-160- Abstract
- Different methods for the synthesis of anionic dimethyl sulfide platinum complexes of the type Q[PtCl3(Me2S)] (Q = triphenylbenzylphosphonium, Ph3PBzl, or tetrabutylammonium, BU4N) and [Pt(mu-Cl)Cl(Me2S)]2 are reported. The compounds Q[PtCl3(Me2S)] were prepared by interaction of [PtCl4]2- with an excess of Me2S in non-aqueous media, reduction of [PtCl5(Me2S)]- with hydrazine sulfate, bridge-splitting reactions of (Ph3PBzl)2[Pt2(mu-Cl)2Cl4] and [Pt(mu-Cl)Cl(Me2S)]2 with two equivalents of Me2S and (Pb3PBzl)Cl, respectively, and substitution of dimethyl sulfide in trans-[PtCl2(Me2S)2]. The [Pt(mu-Cl)Cl(Me2S)]2 dimer was prepared via reaction Of cis-[PtCl2(Me2S)2] with two equivalents of silver nitrate followed by separation of AgCl(s) and... (More)
- Different methods for the synthesis of anionic dimethyl sulfide platinum complexes of the type Q[PtCl3(Me2S)] (Q = triphenylbenzylphosphonium, Ph3PBzl, or tetrabutylammonium, BU4N) and [Pt(mu-Cl)Cl(Me2S)]2 are reported. The compounds Q[PtCl3(Me2S)] were prepared by interaction of [PtCl4]2- with an excess of Me2S in non-aqueous media, reduction of [PtCl5(Me2S)]- with hydrazine sulfate, bridge-splitting reactions of (Ph3PBzl)2[Pt2(mu-Cl)2Cl4] and [Pt(mu-Cl)Cl(Me2S)]2 with two equivalents of Me2S and (Pb3PBzl)Cl, respectively, and substitution of dimethyl sulfide in trans-[PtCl2(Me2S)2]. The [Pt(mu-Cl)Cl(Me2S)]2 dimer was prepared via reaction Of cis-[PtCl2(Me2S)2] with two equivalents of silver nitrate followed by separation of AgCl(s) and addition of one equivalent of K2[PtCl4]. The structure of (Ph3PBzl)[PtCl3(Me2S)] was determined by X-ray single crystal analysis. The compound crystallizes in the space group P2(1)/n with a = 9.746(3), b = 19.511(4), c = 14.966(4) angstrom, beta = 100.43(2)-degrees, V = 2799.0(9) angstrom3 and Z = 4. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/733e8ce9-d38c-4cc4-a3c5-edf840feb83e
- author
- Kukushkin, Vadim Yu. ; Lövqvist, Karin ; Noren, Bertil ; Oskarsson, Åke and Elding, Lars Ivar LU
- organization
- publishing date
- 1994-05
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Synthesis, Platinum(II), Dimethyl sulfide complex
- in
- Inorganica Chimica Acta
- volume
- 219
- issue
- 1-2
- pages
- 155 - 160
- publisher
- Elsevier
- external identifiers
-
- scopus:0011574726
- ISSN
- 0020-1693
- DOI
- 10.1016/0020-1693(94)03845-7
- language
- English
- LU publication?
- yes
- id
- 733e8ce9-d38c-4cc4-a3c5-edf840feb83e
- date added to LUP
- 2017-01-07 21:34:48
- date last changed
- 2021-01-03 10:19:27
@article{733e8ce9-d38c-4cc4-a3c5-edf840feb83e, abstract = {{Different methods for the synthesis of anionic dimethyl sulfide platinum complexes of the type Q[PtCl3(Me2S)] (Q = triphenylbenzylphosphonium, Ph3PBzl, or tetrabutylammonium, BU4N) and [Pt(mu-Cl)Cl(Me2S)]2 are reported. The compounds Q[PtCl3(Me2S)] were prepared by interaction of [PtCl4]2- with an excess of Me2S in non-aqueous media, reduction of [PtCl5(Me2S)]- with hydrazine sulfate, bridge-splitting reactions of (Ph3PBzl)2[Pt2(mu-Cl)2Cl4] and [Pt(mu-Cl)Cl(Me2S)]2 with two equivalents of Me2S and (Pb3PBzl)Cl, respectively, and substitution of dimethyl sulfide in trans-[PtCl2(Me2S)2]. The [Pt(mu-Cl)Cl(Me2S)]2 dimer was prepared via reaction Of cis-[PtCl2(Me2S)2] with two equivalents of silver nitrate followed by separation of AgCl(s) and addition of one equivalent of K2[PtCl4]. The structure of (Ph3PBzl)[PtCl3(Me2S)] was determined by X-ray single crystal analysis. The compound crystallizes in the space group P2(1)/n with a = 9.746(3), b = 19.511(4), c = 14.966(4) angstrom, beta = 100.43(2)-degrees, V = 2799.0(9) angstrom3 and Z = 4.}}, author = {{Kukushkin, Vadim Yu. and Lövqvist, Karin and Noren, Bertil and Oskarsson, Åke and Elding, Lars Ivar}}, issn = {{0020-1693}}, keywords = {{Synthesis; Platinum(II); Dimethyl sulfide complex}}, language = {{eng}}, number = {{1-2}}, pages = {{155--160}}, publisher = {{Elsevier}}, series = {{Inorganica Chimica Acta}}, title = {{New Methods for Synthesis of Platinum(II) Dimethyl Sulfide Complexes}}, url = {{http://dx.doi.org/10.1016/0020-1693(94)03845-7}}, doi = {{10.1016/0020-1693(94)03845-7}}, volume = {{219}}, year = {{1994}}, }