Crystal structure of (piperidine-1-carbo-di-thio-ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II).
(2015) In Acta crystallographica. Section E: Crystallographic communications 71(Pt 9). p.166-166- Abstract
- The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol-ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°. Mol-ecules pack via dispersion inter-actions.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/8035172
- author
- Kondrashov, Mikhail LU ; Fleckhaus, André LU ; Gritcenko, Roman and Wendt, Ola LU
- organization
- publishing date
- 2015
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta crystallographica. Section E: Crystallographic communications
- volume
- 71
- issue
- Pt 9
- pages
- 166 - 166
- publisher
- International Union of Crystallography
- external identifiers
-
- pmid:26396868
- scopus:84953870386
- wos:000370079100007
- pmid:26396868
- ISSN
- 2056-9890
- DOI
- 10.1107/S2056989015015005
- language
- English
- LU publication?
- yes
- id
- 9ae8a29a-dbd4-49ff-afca-b9169086938e (old id 8035172)
- date added to LUP
- 2016-04-04 09:08:44
- date last changed
- 2022-04-15 22:00:58
@article{9ae8a29a-dbd4-49ff-afca-b9169086938e, abstract = {{The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol-ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°. Mol-ecules pack via dispersion inter-actions.}}, author = {{Kondrashov, Mikhail and Fleckhaus, André and Gritcenko, Roman and Wendt, Ola}}, issn = {{2056-9890}}, language = {{eng}}, number = {{Pt 9}}, pages = {{166--166}}, publisher = {{International Union of Crystallography}}, series = {{Acta crystallographica. Section E: Crystallographic communications}}, title = {{Crystal structure of (piperidine-1-carbo-di-thio-ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II).}}, url = {{http://dx.doi.org/10.1107/S2056989015015005}}, doi = {{10.1107/S2056989015015005}}, volume = {{71}}, year = {{2015}}, }