Kinetics of the gas‐phase reactions of chlorine atoms with CH²F², CH³CCl³, and CF³CFH² over the temperature range 253–553 K
(2009) In International Journal of Chemical Kinetics 41(6). p.401-406- Abstract
- Relative rate techniques were used to study the title reactions in 930–1200 mbar of N2 diluent. The reaction rate coefficients measured in the present work are summarized by the expressions k(Cl + CH2F2) = 1.19 × 10−17 T2 exp(−1023/T) cm3 molecule−1 s−1 (253–553 K), k(Cl + CH3CCl3) = 2.41 × 10−12 exp(−1630/T) cm3 molecule−1 s−1 (253–313 K), and k(Cl + CF3CFH2) = 1.27 × 10−12 exp(−2019/T) cm3 molecule−1 s−1 (253–313 K). Results are discussed with respect to the literature data.
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https://lup.lub.lu.se/record/f4ab59a4-883b-489b-b96b-968bc25e2921
- author
- Nilsson, E. J. K. LU ; Johnson, M. S. ; Nielsen, O. J. ; Kaiser, E. W. and Wallington, T. J.
- publishing date
- 2009-06-01
- type
- Contribution to journal
- publication status
- published
- subject
- in
- International Journal of Chemical Kinetics
- volume
- 41
- issue
- 6
- pages
- 6 pages
- publisher
- John Wiley & Sons Inc.
- ISSN
- 0538-8066
- DOI
- 10.1002/kin.v41:6
- language
- English
- LU publication?
- no
- id
- f4ab59a4-883b-489b-b96b-968bc25e2921
- alternative location
- http://doi.wiley.com/10.1002/kin.20398
- date added to LUP
- 2019-05-15 11:13:55
- date last changed
- 2021-08-12 04:15:26
@article{f4ab59a4-883b-489b-b96b-968bc25e2921, abstract = {{Relative rate techniques were used to study the title reactions in 930–1200 mbar of N2 diluent. The reaction rate coefficients measured in the present work are summarized by the expressions k(Cl + CH2F2) = 1.19 × 10−17 T2 exp(−1023/T) cm3 molecule−1 s−1 (253–553 K), k(Cl + CH3CCl3) = 2.41 × 10−12 exp(−1630/T) cm3 molecule−1 s−1 (253–313 K), and k(Cl + CF3CFH2) = 1.27 × 10−12 exp(−2019/T) cm3 molecule−1 s−1 (253–313 K). Results are discussed with respect to the literature data.}}, author = {{Nilsson, E. J. K. and Johnson, M. S. and Nielsen, O. J. and Kaiser, E. W. and Wallington, T. J.}}, issn = {{0538-8066}}, language = {{eng}}, month = {{06}}, number = {{6}}, pages = {{401--406}}, publisher = {{John Wiley & Sons Inc.}}, series = {{International Journal of Chemical Kinetics}}, title = {{Kinetics of the gas‐phase reactions of chlorine atoms with CH²F², CH³CCl³, and CF³CFH² over the temperature range 253–553 K}}, url = {{http://dx.doi.org/10.1002/kin.v41:6}}, doi = {{10.1002/kin.v41:6}}, volume = {{41}}, year = {{2009}}, }