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Iodine Monochloride/Silver Trifluoromethanesulfonate (ICl/AgOTf) as a convenient Promoter System for O-Glycoside Synthesis.

Ercegovic, Teddy LU ; Meijer, Andréas LU ; Magnusson, Göran LU and Ellervik, Ulf LU orcid (2001) In Organic Letters 3(6). p.913-915
Abstract
The novel promoter system iodine monochloride/silver trifluoromethanesulfonate (ICl/AgOTf) was evaluated with various thioglycoside donors and saccharide acceptors, and O-glycosides were obtained in 46−82% yield. Several practical advantages of the ICl/AgOTf system over known promoter systems were observed, such as convenient handling of the reagents and absence of byproducts related to N-succinimide.
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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organic Letters
volume
3
issue
6
pages
913 - 915
publisher
The American Chemical Society (ACS)
external identifiers
  • scopus:0035932570
ISSN
1523-7052
DOI
10.1021/ol015547c
language
English
LU publication?
yes
id
006f5198-cab0-45b0-85f2-b47bd5998adc
date added to LUP
2023-08-10 14:43:41
date last changed
2025-10-14 11:08:35
@article{006f5198-cab0-45b0-85f2-b47bd5998adc,
  abstract     = {{The novel promoter system iodine monochloride/silver trifluoromethanesulfonate (ICl/AgOTf) was evaluated with various thioglycoside donors and saccharide acceptors, and O-glycosides were obtained in 46−82% yield. Several practical advantages of the ICl/AgOTf system over known promoter systems were observed, such as convenient handling of the reagents and absence of byproducts related to N-succinimide.}},
  author       = {{Ercegovic, Teddy and Meijer, Andréas and Magnusson, Göran and Ellervik, Ulf}},
  issn         = {{1523-7052}},
  language     = {{eng}},
  number       = {{6}},
  pages        = {{913--915}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Organic Letters}},
  title        = {{Iodine Monochloride/Silver Trifluoromethanesulfonate (ICl/AgOTf) as a convenient Promoter System for O-Glycoside Synthesis.}},
  url          = {{http://dx.doi.org/10.1021/ol015547c}},
  doi          = {{10.1021/ol015547c}},
  volume       = {{3}},
  year         = {{2001}},
}