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Investigation of the role of Mn dopant in CdS quantum dot sensitized solar cell.

Shen, T. ; Tian, J. ; Lv, L. ; Fei, C. ; Wang, Y. ; Pullerits, Tönu LU and Cao, G. (2016) In Electrochimica Acta p.62-69
Abstract
Mn-doping into CdS quantum dots (QDs) has been demonstrated a useful way to enhance the power conversion efficiency (PCE) of quantum dot sensitized solar cells (QDSCs), the detailed systematic study is needed to get a better fundamental understanding. This work focuses on the study of the effects of Mn dopant on light harvesting, charge transfer, and charge collection of the solar cells. The results indicate that the Mn-doping into CdS QDs increases the light absorbance and extends the light absorption range, which results in the enhancement of the photo-generated current density. In addition, both the electron transport rate and the electron diffusion length are also increased with the introduction of Mn dopant. So the charge collection... (More)
Mn-doping into CdS quantum dots (QDs) has been demonstrated a useful way to enhance the power conversion efficiency (PCE) of quantum dot sensitized solar cells (QDSCs), the detailed systematic study is needed to get a better fundamental understanding. This work focuses on the study of the effects of Mn dopant on light harvesting, charge transfer, and charge collection of the solar cells. The results indicate that the Mn-doping into CdS QDs increases the light absorbance and extends the light absorption range, which results in the enhancement of the photo-generated current density. In addition, both the electron transport rate and the electron diffusion length are also increased with the introduction of Mn dopant. So the charge collection efficiency (ηcc) of the solar cell increases from 89.9% for CdS sample to 96.7% for Mn/CdS sample. As a result, the PCE of Mn/CdS QDSC reaches 3.29%, which is much higher than that of CdS QDSC (2.01%). (Less)
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Electrochimica Acta
pages
62 - 69
publisher
Pergamon Press Ltd.
external identifiers
  • scopus:84955510385
ISSN
0013-4686
language
English
LU publication?
yes
id
07cd9336-6dab-4ece-a9e7-f734335ec234
date added to LUP
2019-09-14 14:21:04
date last changed
2023-09-23 14:40:04
@article{07cd9336-6dab-4ece-a9e7-f734335ec234,
  abstract     = {{Mn-doping into CdS quantum dots (QDs) has been demonstrated a useful way to enhance the power conversion efficiency (PCE) of quantum dot sensitized solar cells (QDSCs), the detailed systematic study is needed to get a better fundamental understanding. This work focuses on the study of the effects of Mn dopant on light harvesting, charge transfer, and charge collection of the solar cells. The results indicate that the Mn-doping into CdS QDs increases the light absorbance and extends the light absorption range, which results in the enhancement of the photo-generated current density. In addition, both the electron transport rate and the electron diffusion length are also increased with the introduction of Mn dopant. So the charge collection efficiency (ηcc) of the solar cell increases from 89.9% for CdS sample to 96.7% for Mn/CdS sample. As a result, the PCE of Mn/CdS QDSC reaches 3.29%, which is much higher than that of CdS QDSC (2.01%).}},
  author       = {{Shen, T. and Tian, J. and Lv, L. and Fei, C. and Wang, Y. and Pullerits, Tönu and Cao, G.}},
  issn         = {{0013-4686}},
  language     = {{eng}},
  pages        = {{62--69}},
  publisher    = {{Pergamon Press Ltd.}},
  series       = {{Electrochimica Acta}},
  title        = {{Investigation of the role of Mn dopant in CdS quantum dot sensitized solar cell.}},
  year         = {{2016}},
}