Axial motion of water hydrogen halide and water halogen complexes in argon matrices
(1986) In The Journal of chemical physics 84(4). p.1981-1987- Abstract
The infrared spectra of the water (H2O, HDO, D2O) complexes with HCl, HBr, HI Cl2, Br2, and I2 have been studied in argon matrices in the 11 to 25 K interval. In all cases, water acts as a lone-pair donor. The hydrogen halide complexes are effectively planar and rotate around the axis through the heavy atoms. For the water halogen complexes, the results are less clear, but a similar rotation, coupled to low wave number bending motions, seems possible.
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https://lup.lub.lu.se/record/1119c2fd-bb15-47dd-8558-76f2719fa8e2
- author
- Engdahl, Anders LU and Nelander, Bengt LU
- organization
- publishing date
- 1986-02-15
- type
- Contribution to journal
- publication status
- published
- subject
- in
- The Journal of chemical physics
- volume
- 84
- issue
- 4
- pages
- 7 pages
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- scopus:36549093825
- ISSN
- 0021-9606
- DOI
- 10.1063/1.450405
- language
- English
- LU publication?
- yes
- additional info
- Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
- id
- 1119c2fd-bb15-47dd-8558-76f2719fa8e2
- date added to LUP
- 2021-03-29 15:29:06
- date last changed
- 2021-10-03 03:43:14
@article{1119c2fd-bb15-47dd-8558-76f2719fa8e2, abstract = {{<p>The infrared spectra of the water (H<sub>2</sub>O, HDO, D<sub>2</sub>O) complexes with HCl, HBr, HI Cl<sub>2</sub>, Br<sub>2</sub>, and I<sub>2</sub> have been studied in argon matrices in the 11 to 25 K interval. In all cases, water acts as a lone-pair donor. The hydrogen halide complexes are effectively planar and rotate around the axis through the heavy atoms. For the water halogen complexes, the results are less clear, but a similar rotation, coupled to low wave number bending motions, seems possible.</p>}}, author = {{Engdahl, Anders and Nelander, Bengt}}, issn = {{0021-9606}}, language = {{eng}}, month = {{02}}, number = {{4}}, pages = {{1981--1987}}, publisher = {{American Institute of Physics (AIP)}}, series = {{The Journal of chemical physics}}, title = {{Axial motion of water hydrogen halide and water halogen complexes in argon matrices}}, url = {{http://dx.doi.org/10.1063/1.450405}}, doi = {{10.1063/1.450405}}, volume = {{84}}, year = {{1986}}, }