Experimental investigation of the Rb-85(2) a (3)Sigma(+)(u) triplet ground state: Multiparameter Morse long range potential analysis
(2009) In Journal of Chemical Physics 131(9).- Abstract
- Using perturbation facilitated infrared-infrared double resonance excitation of the Rb-85(2) molecule, we have observed spectrally resolved fluorescence to the a (3)Sigma(+)(u) state. We have analyzed the rovibrational energy level structure of the Rb-85(2) a (3)Sigma(+)(u) state and derived a multiparameter Morse Long Range (MLR) potential and molecular constants for this state, which can be used to predict term values without needing to solve the radial Schroumldinger equation.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1475160
- author
- Beser, Bediha ; Sovkov, V. B. ; Bai, J. ; Ahmed, E. H. ; Tsai, C. C. ; Xie, F. ; Li, Li ; Ivanov, V. S. and Lyyra, Marjatta LU
- organization
- publishing date
- 2009
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- rotational-vibrational states, optical double resonance, Morse potential, fluorescence, ground states, rubidium, triplet state
- in
- Journal of Chemical Physics
- volume
- 131
- issue
- 9
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000269625400018
- scopus:69949180635
- ISSN
- 0021-9606
- DOI
- 10.1063/1.3194290
- language
- English
- LU publication?
- yes
- id
- 67993da9-9ded-4b82-92f3-8666167f1121 (old id 1475160)
- date added to LUP
- 2016-04-01 12:29:11
- date last changed
- 2022-01-27 05:43:14
@article{67993da9-9ded-4b82-92f3-8666167f1121, abstract = {{Using perturbation facilitated infrared-infrared double resonance excitation of the Rb-85(2) molecule, we have observed spectrally resolved fluorescence to the a (3)Sigma(+)(u) state. We have analyzed the rovibrational energy level structure of the Rb-85(2) a (3)Sigma(+)(u) state and derived a multiparameter Morse Long Range (MLR) potential and molecular constants for this state, which can be used to predict term values without needing to solve the radial Schroumldinger equation.}}, author = {{Beser, Bediha and Sovkov, V. B. and Bai, J. and Ahmed, E. H. and Tsai, C. C. and Xie, F. and Li, Li and Ivanov, V. S. and Lyyra, Marjatta}}, issn = {{0021-9606}}, keywords = {{rotational-vibrational states; optical double resonance; Morse potential; fluorescence; ground states; rubidium; triplet state}}, language = {{eng}}, number = {{9}}, publisher = {{American Institute of Physics (AIP)}}, series = {{Journal of Chemical Physics}}, title = {{Experimental investigation of the Rb-85(2) a (3)Sigma(+)(u) triplet ground state: Multiparameter Morse long range potential analysis}}, url = {{http://dx.doi.org/10.1063/1.3194290}}, doi = {{10.1063/1.3194290}}, volume = {{131}}, year = {{2009}}, }