The gas phase reaction between CO2 and lanthanide atoms. A test of a model for the isokinetic effect
(2005) In Reaction Kinetics and Catalysis Letters 85(1). p.107-113- Abstract
- Using literature data on the gas phase reaction between free lanthanide atoms and carbon dioxide, we have found an isokinetic relation for seven of the twelve investigated elements with an isokinetic temperature, T-iso of 2500 +/- 330 K. This value is analyzed in the framework of the model of selective energy transfer, SET, indicating that metal-CO2 complexes are formed as pre-reaction states. The result is in accordance with the fundamental concepts of SET.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/151680
- author
- Larsson, Ragnar LU and Mascetti, J
- organization
- publishing date
- 2005
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Reaction Kinetics and Catalysis Letters
- volume
- 85
- issue
- 1
- pages
- 107 - 113
- publisher
- Springer
- external identifiers
-
- wos:000229721100014
- scopus:21144445795
- ISSN
- 1588-2837
- DOI
- 10.1007/s11144-005-0249-7
- language
- English
- LU publication?
- yes
- id
- 6b1b7fc8-5499-4ebf-a9af-2a45760e3c3c (old id 151680)
- date added to LUP
- 2016-04-01 12:05:49
- date last changed
- 2023-11-26 01:29:53
@article{6b1b7fc8-5499-4ebf-a9af-2a45760e3c3c, abstract = {{Using literature data on the gas phase reaction between free lanthanide atoms and carbon dioxide, we have found an isokinetic relation for seven of the twelve investigated elements with an isokinetic temperature, T-iso of 2500 +/- 330 K. This value is analyzed in the framework of the model of selective energy transfer, SET, indicating that metal-CO2 complexes are formed as pre-reaction states. The result is in accordance with the fundamental concepts of SET.}}, author = {{Larsson, Ragnar and Mascetti, J}}, issn = {{1588-2837}}, language = {{eng}}, number = {{1}}, pages = {{107--113}}, publisher = {{Springer}}, series = {{Reaction Kinetics and Catalysis Letters}}, title = {{The gas phase reaction between CO2 and lanthanide atoms. A test of a model for the isokinetic effect}}, url = {{http://dx.doi.org/10.1007/s11144-005-0249-7}}, doi = {{10.1007/s11144-005-0249-7}}, volume = {{85}}, year = {{2005}}, }