Electrolytes based on LiClO4 and branched PEG-boronate ester polymers for electrochromics
Pennarun, Pierre-Yves LU and Jannasch, Patric LU
(2005)
In Solid State Ionics
176(11-12).
p.1103-1112
- Abstract
- Structure-property relationships of polymers incorporating Lewis acidic boron in their branched chain architecture were investigated as a function of LiClO4 salt concentration. The polymers were synthesised from boron trioxide, and different poly(ethylene glycol)s (PEGs) and monomethyl ether end-capped PEGs. The PEG-boronate ester polymers based on PEGs having molecular weights equal to, or below, 300 g/mol were found to be amorphous, colourless, and highly transparent. Electrolytes derived from these polymers and LiClO4 reached ionic conductivities up to 10(-4) S cm(-1) at room temperature, and were thermally stable up to at least 150 ° C. A number of electrolytes showed a combination of attractive properties which made them... (More)
- Structure-property relationships of polymers incorporating Lewis acidic boron in their branched chain architecture were investigated as a function of LiClO4 salt concentration. The polymers were synthesised from boron trioxide, and different poly(ethylene glycol)s (PEGs) and monomethyl ether end-capped PEGs. The PEG-boronate ester polymers based on PEGs having molecular weights equal to, or below, 300 g/mol were found to be amorphous, colourless, and highly transparent. Electrolytes derived from these polymers and LiClO4 reached ionic conductivities up to 10(-4) S cm(-1) at room temperature, and were thermally stable up to at least 150 ° C. A number of electrolytes showed a combination of attractive properties which made them interesting for use in electrochromic devices. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/153063
- author
- Pennarun, Pierre-Yves
LU
and Jannasch, Patric
LU
- organization
- publishing date
- 2005
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Solid State Ionics
- volume
- 176
- issue
- 11-12
- pages
- 1103 - 1112
- publisher
- Elsevier
- external identifiers
-
- wos:000228981600015
- scopus:15944363045
- ISSN
- 0167-2738
- DOI
- 10.1016/j.ssi.2005.01.001
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- 0ba63470-d501-4de3-9a3f-fe1d38e3046d (old id 153063)
- date added to LUP
- 2016-04-01 12:16:58
- date last changed
- 2022-01-27 01:28:32
@article{0ba63470-d501-4de3-9a3f-fe1d38e3046d,
abstract = {{Structure-property relationships of polymers incorporating Lewis acidic boron in their branched chain architecture were investigated as a function of LiClO4 salt concentration. The polymers were synthesised from boron trioxide, and different poly(ethylene glycol)s (PEGs) and monomethyl ether end-capped PEGs. The PEG-boronate ester polymers based on PEGs having molecular weights equal to, or below, 300 g/mol were found to be amorphous, colourless, and highly transparent. Electrolytes derived from these polymers and LiClO4 reached ionic conductivities up to 10(-4) S cm(-1) at room temperature, and were thermally stable up to at least 150 ° C. A number of electrolytes showed a combination of attractive properties which made them interesting for use in electrochromic devices.}},
author = {{Pennarun, Pierre-Yves and Jannasch, Patric}},
issn = {{0167-2738}},
language = {{eng}},
number = {{11-12}},
pages = {{1103--1112}},
publisher = {{Elsevier}},
series = {{Solid State Ionics}},
title = {{Electrolytes based on LiClO4 and branched PEG-boronate ester polymers for electrochromics}},
url = {{http://dx.doi.org/10.1016/j.ssi.2005.01.001}},
doi = {{10.1016/j.ssi.2005.01.001}},
volume = {{176}},
year = {{2005}},
}