Matrix infrared spectra and electronic structure calculations of the first actinide borylene: FB=ThF2
(2010) In Chemical Communications 46(10). p.1646-1648- Abstract
- Laser-ablated Th atoms react with BF3 during condensation in excess argon at 6 K to form the first actinide borylene (FB=ThF2) and actinide-boron multiple bond. Three new product absorptions in the B-F and Th-F stretching regions of matrix infrared spectra are assigned to FB=ThF2 from comparison to theoretically predicted vibrational frequencies.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1568306
- author
- Wang, Xuefeng ; Roos, Björn LU and Andrews, Lester
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Communications
- volume
- 46
- issue
- 10
- pages
- 1646 - 1648
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000274827000013
- scopus:77249157005
- pmid:20177603
- ISSN
- 1364-548X
- DOI
- 10.1039/b923195a
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039)
- id
- 442cb472-9505-47ef-902b-b333ff0ad94a (old id 1568306)
- date added to LUP
- 2016-04-01 11:00:22
- date last changed
- 2023-01-02 17:55:07
@article{442cb472-9505-47ef-902b-b333ff0ad94a, abstract = {{Laser-ablated Th atoms react with BF3 during condensation in excess argon at 6 K to form the first actinide borylene (FB=ThF2) and actinide-boron multiple bond. Three new product absorptions in the B-F and Th-F stretching regions of matrix infrared spectra are assigned to FB=ThF2 from comparison to theoretically predicted vibrational frequencies.}}, author = {{Wang, Xuefeng and Roos, Björn and Andrews, Lester}}, issn = {{1364-548X}}, language = {{eng}}, number = {{10}}, pages = {{1646--1648}}, publisher = {{Royal Society of Chemistry}}, series = {{Chemical Communications}}, title = {{Matrix infrared spectra and electronic structure calculations of the first actinide borylene: FB=ThF2}}, url = {{http://dx.doi.org/10.1039/b923195a}}, doi = {{10.1039/b923195a}}, volume = {{46}}, year = {{2010}}, }