Hexakis(tetraaquasodium) decavanadate(V) dihydrate
(2010) In Acta Crystallographica Section E: Structure Reports Online 66. p.30-148- Abstract
- The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1587189
- author
- Nilsson, Jessica LU ; Nordlander, Ebbe LU ; Behrens, Ulrich and Rehder, Dieter
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta Crystallographica Section E: Structure Reports Online
- volume
- 66
- pages
- 30 - 148
- publisher
- International Union of Crystallography
- external identifiers
-
- wos:000276190700004
- scopus:77951236065
- pmid:21580463
- ISSN
- 1600-5368
- DOI
- 10.1107/S1600536810010251
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- 64a56dff-4d55-4a55-921f-ff7f2516fc68 (old id 1587189)
- date added to LUP
- 2016-04-01 14:09:06
- date last changed
- 2022-01-27 23:01:22
@article{64a56dff-4d55-4a55-921f-ff7f2516fc68, abstract = {{The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.}}, author = {{Nilsson, Jessica and Nordlander, Ebbe and Behrens, Ulrich and Rehder, Dieter}}, issn = {{1600-5368}}, language = {{eng}}, pages = {{30--148}}, publisher = {{International Union of Crystallography}}, series = {{Acta Crystallographica Section E: Structure Reports Online}}, title = {{Hexakis(tetraaquasodium) decavanadate(V) dihydrate}}, url = {{http://dx.doi.org/10.1107/S1600536810010251}}, doi = {{10.1107/S1600536810010251}}, volume = {{66}}, year = {{2010}}, }