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Nuclear motion in carbonyl sulfide induced by resonant core electron excitation

Laksman, Joakim LU ; Céolin, Denis LU ; Gisselbrecht, Mathieu LU orcid and Ristinmaa Sörensen, Stacey LU orcid (2010) In Journal of Chemical Physics 133(14). p.1-144314
Abstract
The angular anisotropy for selected dissociation channels is measured at resonantly excited states of and symmetries at the C and O K-shell ionization edges of carbonyl sulfide.

While the kinetic energy released in the reaction is mainly independent of the excitation energy, the angular anisotropy and momentum correlation clearly show deformation of the OCS molecule in the C1s−Pi state.

The discovery of a two-body fragmentation channel SO+/C+ with a well defined angular anisotropy indicates the rapid formation of the CSO isomeric species.
Please use this url to cite or link to this publication:
author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
OCS
in
Journal of Chemical Physics
volume
133
issue
14
pages
1 - 144314
publisher
American Institute of Physics (AIP)
external identifiers
  • wos:000283200400030
  • scopus:77958111330
  • pmid:20950007
ISSN
0021-9606
DOI
10.1063/1.3502116
language
English
LU publication?
yes
id
ceef525a-dc23-476b-860d-797a0bb7de3a (old id 1692601)
date added to LUP
2016-04-01 09:58:02
date last changed
2025-10-14 12:19:21
@article{ceef525a-dc23-476b-860d-797a0bb7de3a,
  abstract     = {{The angular anisotropy for selected dissociation channels is measured at resonantly excited states of and symmetries at the C and O K-shell ionization edges of carbonyl sulfide.<br/><br>
While the kinetic energy released in the reaction is mainly independent of the excitation energy, the angular anisotropy and momentum correlation clearly show deformation of the OCS molecule in the C1s−Pi state.<br/><br>
The discovery of a two-body fragmentation channel SO+/C+ with a well defined angular anisotropy indicates the rapid formation of the CSO isomeric species.}},
  author       = {{Laksman, Joakim and Céolin, Denis and Gisselbrecht, Mathieu and Ristinmaa Sörensen, Stacey}},
  issn         = {{0021-9606}},
  keywords     = {{OCS}},
  language     = {{eng}},
  number       = {{14}},
  pages        = {{1--144314}},
  publisher    = {{American Institute of Physics (AIP)}},
  series       = {{Journal of Chemical Physics}},
  title        = {{Nuclear motion in carbonyl sulfide induced by resonant core electron excitation}},
  url          = {{https://lup.lub.lu.se/search/files/1432281/1692602.pdf}},
  doi          = {{10.1063/1.3502116}},
  volume       = {{133}},
  year         = {{2010}},
}