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Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]

Johnson, Magnus LU and Wendt, Ola LU (2011) In Inorganica Chimica Acta 367(1). p.222-224
Abstract
The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Nickel, Phosphine, Cyclometallation, Pincer ligands
in
Inorganica Chimica Acta
volume
367
issue
1
pages
222 - 224
publisher
Elsevier
external identifiers
  • wos:000286930000032
  • scopus:79551681273
ISSN
0020-1693
DOI
10.1016/j.ica.2010.12.007
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
e2c1b6dd-c2ee-4308-b5ac-561e22cf28ca (old id 1872840)
date added to LUP
2016-04-01 14:32:28
date last changed
2022-01-28 01:08:30
@article{e2c1b6dd-c2ee-4308-b5ac-561e22cf28ca,
  abstract     = {{The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.}},
  author       = {{Johnson, Magnus and Wendt, Ola}},
  issn         = {{0020-1693}},
  keywords     = {{Nickel; Phosphine; Cyclometallation; Pincer ligands}},
  language     = {{eng}},
  number       = {{1}},
  pages        = {{222--224}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]}},
  url          = {{http://dx.doi.org/10.1016/j.ica.2010.12.007}},
  doi          = {{10.1016/j.ica.2010.12.007}},
  volume       = {{367}},
  year         = {{2011}},
}