[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate
(2011) In Acta Crystallographica Section E: Structure Reports Online 67(12). p.1601-1816- Abstract
- In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2345073
- author
- Abdel-Magied, Ahmed ; Singh, Amrendra LU ; Haukka, Matti and Nordlander, Ebbe LU
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta Crystallographica Section E: Structure Reports Online
- volume
- 67
- issue
- 12
- pages
- 1601 - 1816
- publisher
- International Union of Crystallography
- external identifiers
-
- wos:000298795300129
- scopus:83155184854
- ISSN
- 1600-5368
- DOI
- 10.1107/S1600536811049312
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- 4025bb82-aca3-4a7c-b9ed-ab7d558ea290 (old id 2345073)
- date added to LUP
- 2016-04-01 14:29:41
- date last changed
- 2022-01-28 00:51:57
@article{4025bb82-aca3-4a7c-b9ed-ab7d558ea290, abstract = {{In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.}}, author = {{Abdel-Magied, Ahmed and Singh, Amrendra and Haukka, Matti and Nordlander, Ebbe}}, issn = {{1600-5368}}, language = {{eng}}, number = {{12}}, pages = {{1601--1816}}, publisher = {{International Union of Crystallography}}, series = {{Acta Crystallographica Section E: Structure Reports Online}}, title = {{[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate}}, url = {{http://dx.doi.org/10.1107/S1600536811049312}}, doi = {{10.1107/S1600536811049312}}, volume = {{67}}, year = {{2011}}, }