From localised to delocalised electronic states in free Ar, Kr and Xe clusters
(2004) In European Physical Journal D. Atomic, Molecular, Optical and Plasma Physics 30(3). p.343-351- Abstract
- We present new results for the inner valence levels of clusters of the three inert gases Ar, Kr and Xe based on photoelectron spectroscopy studies. The inner valence levels are compared to the localised core levels and to the delocalised outer valence levels. This comparison shows a gradual change from a relatively localised behaviour for Ar inner valence 3s, over the intermediate case of Kr inner valence 4s, to a more delocalised behaviour for Xe inner valence 5s. This change correlates well with the ratio between the orbital sizes and the interatomic distances. The Kr4s intermediate case is found to exhibit characteristics of both localised and delocalised behaviour.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/266510
- author
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- in
- European Physical Journal D. Atomic, Molecular, Optical and Plasma Physics
- volume
- 30
- issue
- 3
- pages
- 343 - 351
- publisher
- EDP Sciences
- external identifiers
-
- wos:000224301400006
- scopus:4944219653
- ISSN
- 1434-6060
- DOI
- 10.1140/epjd/e2004-00103-6
- language
- English
- LU publication?
- yes
- id
- c4249210-dd1c-48c0-8c9f-bcc7a7774094 (old id 266510)
- date added to LUP
- 2016-04-01 16:43:00
- date last changed
- 2024-01-11 13:25:00
@article{c4249210-dd1c-48c0-8c9f-bcc7a7774094, abstract = {{We present new results for the inner valence levels of clusters of the three inert gases Ar, Kr and Xe based on photoelectron spectroscopy studies. The inner valence levels are compared to the localised core levels and to the delocalised outer valence levels. This comparison shows a gradual change from a relatively localised behaviour for Ar inner valence 3s, over the intermediate case of Kr inner valence 4s, to a more delocalised behaviour for Xe inner valence 5s. This change correlates well with the ratio between the orbital sizes and the interatomic distances. The Kr4s intermediate case is found to exhibit characteristics of both localised and delocalised behaviour.}}, author = {{Feifel, R and Tchaplyguine, Maxim and Ohrwall, G and Salonen, M and Lundwall, M and Marinho, RRT and Gisselbrecht, Mathieu and Ristinmaa Sörensen, Stacey and de Brito, AN and Karlsson, L and Martensson, N and Svensson, S and Bjorneholm, O}}, issn = {{1434-6060}}, language = {{eng}}, number = {{3}}, pages = {{343--351}}, publisher = {{EDP Sciences}}, series = {{European Physical Journal D. Atomic, Molecular, Optical and Plasma Physics}}, title = {{From localised to delocalised electronic states in free Ar, Kr and Xe clusters}}, url = {{http://dx.doi.org/10.1140/epjd/e2004-00103-6}}, doi = {{10.1140/epjd/e2004-00103-6}}, volume = {{30}}, year = {{2004}}, }