Self-assembly of chiral bicyclic keto-alcohols into supramolecular helices in the solid state
(2002) In CrystEngComm p.146-148- Abstract
- The bicyclic keto-alcohol (1S,4R,6S)-bicyclo[2.2.2]octan-6-ol-2-one, (+)-3, self-assembles in the solid state through hydrogen bonds between the alcohol and the carbonyl groups creating supramolecular helices, without the aid of other forces such as pi-pi interactions to stabilise the superstructure. Furthermore, the bicyclic compound (4) although structurally quite different, in relation to (+)-3, also formed supramolecular helix in similar fashion.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/335248
- author
- Sarvary, Ian LU ; Johansson, Maria and Frejd, Torbjörn LU
- organization
- publishing date
- 2002
- type
- Contribution to journal
- publication status
- published
- subject
- in
- CrystEngComm
- pages
- 146 - 148
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000176247700001
- scopus:2942643740
- ISSN
- 1466-8033
- DOI
- 10.1039/b202761e
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- 3290ea03-ce76-4d2e-b90f-288b41e724a8 (old id 335248)
- date added to LUP
- 2016-04-01 15:50:30
- date last changed
- 2022-02-27 17:05:43
@article{3290ea03-ce76-4d2e-b90f-288b41e724a8, abstract = {{The bicyclic keto-alcohol (1S,4R,6S)-bicyclo[2.2.2]octan-6-ol-2-one, (+)-3, self-assembles in the solid state through hydrogen bonds between the alcohol and the carbonyl groups creating supramolecular helices, without the aid of other forces such as pi-pi interactions to stabilise the superstructure. Furthermore, the bicyclic compound (4) although structurally quite different, in relation to (+)-3, also formed supramolecular helix in similar fashion.}}, author = {{Sarvary, Ian and Johansson, Maria and Frejd, Torbjörn}}, issn = {{1466-8033}}, language = {{eng}}, pages = {{146--148}}, publisher = {{Royal Society of Chemistry}}, series = {{CrystEngComm}}, title = {{Self-assembly of chiral bicyclic keto-alcohols into supramolecular helices in the solid state}}, url = {{http://dx.doi.org/10.1039/b202761e}}, doi = {{10.1039/b202761e}}, year = {{2002}}, }