Mapping potential energy surfaces by core electron excitation: the resonant Auger decay spectrum of BF3
(2002) In Chemical Physics Letters 359(1-2). p.48-54- Abstract
- High-resolution electron spectroscopy applied under resonant Auger-Raman conditions is shown to be a powerful tool for characterizing complex potential energy surfaces of core-excited states in polyatomic systems. BF3 is used as a prototype molecule: excitation of the Bls --> 2a(2)(") transition leads to an exceptional out-of-plane vibrational excitation resolved over a wide energy range (3.6 eV). The photon energy dependence of the spectra through the resonance profile is rationalized in the frame of the relative slopes of the potential energy curves along the boron out-of-plane displacement coordinate.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/335264
- author
- Miron, C ; Feifel, R ; Bjorneholm, O ; Svensson, S ; de Brito, AN ; Ristinmaa Sörensen, Stacey LU ; Piancastelli, MN ; Simon, M and Morin, P
- organization
- publishing date
- 2002
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics Letters
- volume
- 359
- issue
- 1-2
- pages
- 48 - 54
- publisher
- Elsevier
- external identifiers
-
- wos:000176372500008
- scopus:0037071696
- ISSN
- 0009-2614
- DOI
- 10.1016/S0009-2614(02)00627-9
- language
- English
- LU publication?
- yes
- id
- 25ce8b13-3588-4948-8141-9a8156402b67 (old id 335264)
- date added to LUP
- 2016-04-01 15:41:21
- date last changed
- 2024-05-24 15:30:09
@article{25ce8b13-3588-4948-8141-9a8156402b67, abstract = {{High-resolution electron spectroscopy applied under resonant Auger-Raman conditions is shown to be a powerful tool for characterizing complex potential energy surfaces of core-excited states in polyatomic systems. BF3 is used as a prototype molecule: excitation of the Bls --> 2a(2)(") transition leads to an exceptional out-of-plane vibrational excitation resolved over a wide energy range (3.6 eV). The photon energy dependence of the spectra through the resonance profile is rationalized in the frame of the relative slopes of the potential energy curves along the boron out-of-plane displacement coordinate.}}, author = {{Miron, C and Feifel, R and Bjorneholm, O and Svensson, S and de Brito, AN and Ristinmaa Sörensen, Stacey and Piancastelli, MN and Simon, M and Morin, P}}, issn = {{0009-2614}}, language = {{eng}}, number = {{1-2}}, pages = {{48--54}}, publisher = {{Elsevier}}, series = {{Chemical Physics Letters}}, title = {{Mapping potential energy surfaces by core electron excitation: the resonant Auger decay spectrum of BF3}}, url = {{http://dx.doi.org/10.1016/S0009-2614(02)00627-9}}, doi = {{10.1016/S0009-2614(02)00627-9}}, volume = {{359}}, year = {{2002}}, }