Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction
(2002) In Organometallics 21(8). p.1583-1590- Abstract
- The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/340179
- author
- Bjurling, Emelie LU ; Berg, Ulf LU and Andersson, CM
- organization
- publishing date
- 2002
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Organometallics
- volume
- 21
- issue
- 8
- pages
- 1583 - 1590
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000175025900012
- scopus:0013219335
- ISSN
- 1520-6041
- DOI
- 10.1021/om011016g
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- d0d18f8f-5ee8-4d4a-8c8b-a4e5ccdfc47e (old id 340179)
- date added to LUP
- 2016-04-01 12:11:52
- date last changed
- 2022-02-26 03:13:47
@article{d0d18f8f-5ee8-4d4a-8c8b-a4e5ccdfc47e, abstract = {{The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.}}, author = {{Bjurling, Emelie and Berg, Ulf and Andersson, CM}}, issn = {{1520-6041}}, language = {{eng}}, number = {{8}}, pages = {{1583--1590}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Organometallics}}, title = {{Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction}}, url = {{http://dx.doi.org/10.1021/om011016g}}, doi = {{10.1021/om011016g}}, volume = {{21}}, year = {{2002}}, }