Vibrational modes of oxygen dimers in germanium
(2002) In Solid State Phenomena 82-84. p.105-110- Abstract
- Infrared absorption of as-grown, heat-treated and electron irradiated Ge crystals enriched with either O-16 or O-18 oxygen isotopes has been studied. Vibrational absorption bands at 780, 818 and 857 cm(-1) (741, 776 and 811 cm(-1)) are assigned to di-oxygen complexes (dimers) in Ge: O-16 (O-18). This assignment is based on an analysis of positions and isotopic shifts of the lines as well as on an investigation of dependencies of line intensities on heat-treatment temperature and oxygen content in the crystals. It is argued that there are two configurations of oxygen dimers in Ge, the bands at 780 and 818 cm(-1) being related to one of them and the band at 857 cm(-1) to another. The binding energy of the dimer giving rise to the bands at... (More)
- Infrared absorption of as-grown, heat-treated and electron irradiated Ge crystals enriched with either O-16 or O-18 oxygen isotopes has been studied. Vibrational absorption bands at 780, 818 and 857 cm(-1) (741, 776 and 811 cm(-1)) are assigned to di-oxygen complexes (dimers) in Ge: O-16 (O-18). This assignment is based on an analysis of positions and isotopic shifts of the lines as well as on an investigation of dependencies of line intensities on heat-treatment temperature and oxygen content in the crystals. It is argued that there are two configurations of oxygen dimers in Ge, the bands at 780 and 818 cm(-1) being related to one of them and the band at 857 cm(-1) to another. The binding energy of the dimer giving rise to the bands at 780 and 818 cm(-1) is estimated to be about 0.35-0.4 eV. (Less)
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https://lup.lub.lu.se/record/349010
- author
- Litvinov, VV ; Murin, LI ; Lindström, Lennart LU ; Markevich, VP and Klechko, AA
- organization
- publishing date
- 2002
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- oxygen dimer, oxygen, germanium, local vibrational modes
- in
- Solid State Phenomena
- volume
- 82-84
- pages
- 105 - 110
- publisher
- Trans Tech Publications
- external identifiers
-
- wos:000172421600016
- scopus:0036131642
- ISSN
- 1012-0394
- language
- English
- LU publication?
- yes
- id
- 3e033c45-ea84-4a0c-a73f-84ed1e1b2726 (old id 349010)
- date added to LUP
- 2016-04-01 15:41:48
- date last changed
- 2025-10-14 11:21:26
@article{3e033c45-ea84-4a0c-a73f-84ed1e1b2726,
abstract = {{Infrared absorption of as-grown, heat-treated and electron irradiated Ge crystals enriched with either O-16 or O-18 oxygen isotopes has been studied. Vibrational absorption bands at 780, 818 and 857 cm(-1) (741, 776 and 811 cm(-1)) are assigned to di-oxygen complexes (dimers) in Ge: O-16 (O-18). This assignment is based on an analysis of positions and isotopic shifts of the lines as well as on an investigation of dependencies of line intensities on heat-treatment temperature and oxygen content in the crystals. It is argued that there are two configurations of oxygen dimers in Ge, the bands at 780 and 818 cm(-1) being related to one of them and the band at 857 cm(-1) to another. The binding energy of the dimer giving rise to the bands at 780 and 818 cm(-1) is estimated to be about 0.35-0.4 eV.}},
author = {{Litvinov, VV and Murin, LI and Lindström, Lennart and Markevich, VP and Klechko, AA}},
issn = {{1012-0394}},
keywords = {{oxygen dimer; oxygen; germanium; local vibrational modes}},
language = {{eng}},
pages = {{105--110}},
publisher = {{Trans Tech Publications}},
series = {{Solid State Phenomena}},
title = {{Vibrational modes of oxygen dimers in germanium}},
volume = {{82-84}},
year = {{2002}},
}