Well-defined phosphonated homo- and copolymers via direct ring opening metathesis polymerization
Bingöl, Bahar LU ; Kröger, Anja and Jannasch, Patric LU
(2013)
In Polymer
54(25).
p.6676-6688
- Abstract
- Phosphonated polymers with a well-defined molecular weight, composition, and architecture have been prepared via ring opening metathesis polymerization (ROMP) of diethyl phosphonate norbornene imides at room temperature for the first time. ROMP gave a broad range of phosphonated homopolymers, statistical, diblock and triblock copolymers based on poly(norbornene imide)s with low polydispersity (1.09-1.32) Complete hydrolysis of diethyl phosphonate poly(norbornene imide)s under mild conditions yielded the phosphonic acid derivatives. Thermogravimetric analysis indicated high thermal and thermo-oxidative stability of the polymers. Free standing and transparent films with good mechanical stability were obtained from the phosphonic acid... (More)
- Phosphonated polymers with a well-defined molecular weight, composition, and architecture have been prepared via ring opening metathesis polymerization (ROMP) of diethyl phosphonate norbornene imides at room temperature for the first time. ROMP gave a broad range of phosphonated homopolymers, statistical, diblock and triblock copolymers based on poly(norbornene imide)s with low polydispersity (1.09-1.32) Complete hydrolysis of diethyl phosphonate poly(norbornene imide)s under mild conditions yielded the phosphonic acid derivatives. Thermogravimetric analysis indicated high thermal and thermo-oxidative stability of the polymers. Free standing and transparent films with good mechanical stability were obtained from the phosphonic acid functional homopolymers, diblock and triblock copolymers. Combining these basic properties with the advantages mentioned above make ROMP a promising pathway for accessing a wide diversity of phosphonated macromolecular structures. These new phosphonated polymers will open new perspectives in advanced application areas such as medicine and membrane science, which require a high level of control over polymer structure. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3631061
- author
- Bingöl, Bahar
LU
; Kröger, Anja
and Jannasch, Patric
LU
- organization
- publishing date
- 2013
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Polymer
- volume
- 54
- issue
- 25
- pages
- 6676 - 6688
- publisher
- Elsevier
- external identifiers
-
- wos:000327418600002
- scopus:84888003486
- ISSN
- 0032-3861
- DOI
- 10.1016/j.polymer.2013.10.018
- language
- English
- LU publication?
- yes
- additional info
- The research leading to these results has received funding from the European Community’s Seventh Framework Programme (FP7/2010–2013) under the call ENERGY-2010-10.2-1: Future Emerging Technologies for Energy Applications (FET) under contract 256821 QuasiDry.
- id
- db082952-aea8-48e7-94fa-b284177b7c7e (old id 3631061)
- alternative location
- http://www.sciencedirect.com/science/article/pii/S0032386113009609
- date added to LUP
- 2016-04-01 13:23:28
- date last changed
- 2022-01-27 18:57:36
@article{db082952-aea8-48e7-94fa-b284177b7c7e,
abstract = {{Phosphonated polymers with a well-defined molecular weight, composition, and architecture have been prepared via ring opening metathesis polymerization (ROMP) of diethyl phosphonate norbornene imides at room temperature for the first time. ROMP gave a broad range of phosphonated homopolymers, statistical, diblock and triblock copolymers based on poly(norbornene imide)s with low polydispersity (1.09-1.32) Complete hydrolysis of diethyl phosphonate poly(norbornene imide)s under mild conditions yielded the phosphonic acid derivatives. Thermogravimetric analysis indicated high thermal and thermo-oxidative stability of the polymers. Free standing and transparent films with good mechanical stability were obtained from the phosphonic acid functional homopolymers, diblock and triblock copolymers. Combining these basic properties with the advantages mentioned above make ROMP a promising pathway for accessing a wide diversity of phosphonated macromolecular structures. These new phosphonated polymers will open new perspectives in advanced application areas such as medicine and membrane science, which require a high level of control over polymer structure.}},
author = {{Bingöl, Bahar and Kröger, Anja and Jannasch, Patric}},
issn = {{0032-3861}},
language = {{eng}},
number = {{25}},
pages = {{6676--6688}},
publisher = {{Elsevier}},
series = {{Polymer}},
title = {{Well-defined phosphonated homo- and copolymers via direct ring opening metathesis polymerization}},
url = {{http://dx.doi.org/10.1016/j.polymer.2013.10.018}},
doi = {{10.1016/j.polymer.2013.10.018}},
volume = {{54}},
year = {{2013}},
}