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Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide

Zvezdina, S. V. ; Mal'tseva, O. V. ; Chizhova, N. V. ; Scheblykin, Ivan LU orcid and Mamardashvili, N. Zh. (2013) In Russian Journal of Inorganic Chemistry 58(4). p.486-490
Abstract
The metal-exchange reaction of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with copper acetate (Cu(OAc)(2)) in dimethylformamide was studied spectrophotometrically. The kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Russian Journal of Inorganic Chemistry
volume
58
issue
4
pages
486 - 490
publisher
MAIK Nauka/Interperiodica
external identifiers
  • wos:000318284000019
  • scopus:84879852457
ISSN
0036-0236
DOI
10.1134/S0036023613040219
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
b8b1c6f1-301e-42c6-8b78-693434944d07 (old id 3851460)
date added to LUP
2016-04-01 10:23:10
date last changed
2022-01-25 22:41:17
@article{b8b1c6f1-301e-42c6-8b78-693434944d07,
  abstract     = {{The metal-exchange reaction of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with copper acetate (Cu(OAc)(2)) in dimethylformamide was studied spectrophotometrically. The kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.}},
  author       = {{Zvezdina, S. V. and Mal'tseva, O. V. and Chizhova, N. V. and Scheblykin, Ivan and Mamardashvili, N. Zh.}},
  issn         = {{0036-0236}},
  language     = {{eng}},
  number       = {{4}},
  pages        = {{486--490}},
  publisher    = {{MAIK Nauka/Interperiodica}},
  series       = {{Russian Journal of Inorganic Chemistry}},
  title        = {{Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide}},
  url          = {{http://dx.doi.org/10.1134/S0036023613040219}},
  doi          = {{10.1134/S0036023613040219}},
  volume       = {{58}},
  year         = {{2013}},
}