Dissociation dynamics of the diamondoid adamantane upon photoionization by XUV femtosecond pulses
Maclot, Sylvain LU ; Lahl, Jan LU ; Peschel, Jasper LU ; Wikmark, Hampus LU
; Rudawski, Piotr
LU
; Brunner, Fabian
LU
; Coudert-Alteirac, Hélène
LU
; Indrajith, Suvasthika
; Huber, Bernd A
and Díaz-Tendero, Sergio
, et al.
(2020)
In Scientific Reports
10(1).
- Abstract
This work presents a photodissociation study of the diamondoid adamantane using extreme ultraviolet femtosecond pulses. The fragmentation dynamics of the dication is unraveled by the use of advanced ion and electron spectroscopy giving access to the dissociation channels as well as their energetics. To get insight into the fragmentation dynamics, we use a theoretical approach combining potential energy surface determination, statistical fragmentation methods and molecular dynamics simulations. We demonstrate that the dissociation dynamics of adamantane dications takes place in a two-step process: barrierless cage opening followed by Coulomb repulsion-driven fragmentation.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3aa95e7a-05bd-4f06-a4ae-2e8b164aae06
- author
- Maclot, Sylvain
LU
; Lahl, Jan
LU
; Peschel, Jasper
LU
; Wikmark, Hampus
LU
; Rudawski, Piotr
LU
; Brunner, Fabian
LU
; Coudert-Alteirac, Hélène
LU
; Indrajith, Suvasthika
; Huber, Bernd A
and Díaz-Tendero, Sergio
, et al. (More)
- Maclot, Sylvain
LU
; Lahl, Jan
LU
; Peschel, Jasper
LU
; Wikmark, Hampus
LU
; Rudawski, Piotr
LU
; Brunner, Fabian
LU
; Coudert-Alteirac, Hélène
LU
; Indrajith, Suvasthika
; Huber, Bernd A
; Díaz-Tendero, Sergio
; Aguirre, Néstor F
; Rousseau, Patrick
and Johnsson, Per
LU
(Less)
- organization
- publishing date
- 2020-02-19
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Scientific Reports
- volume
- 10
- issue
- 1
- article number
- 2884
- publisher
- Nature Publishing Group
- external identifiers
-
- scopus:85079806770
- pmid:32076001
- ISSN
- 2045-2322
- DOI
- 10.1038/s41598-020-59649-1
- language
- English
- LU publication?
- yes
- id
- 3aa95e7a-05bd-4f06-a4ae-2e8b164aae06
- date added to LUP
- 2020-02-24 16:02:03
- date last changed
- 2024-06-26 11:56:17
@article{3aa95e7a-05bd-4f06-a4ae-2e8b164aae06,
abstract = {{<p>This work presents a photodissociation study of the diamondoid adamantane using extreme ultraviolet femtosecond pulses. The fragmentation dynamics of the dication is unraveled by the use of advanced ion and electron spectroscopy giving access to the dissociation channels as well as their energetics. To get insight into the fragmentation dynamics, we use a theoretical approach combining potential energy surface determination, statistical fragmentation methods and molecular dynamics simulations. We demonstrate that the dissociation dynamics of adamantane dications takes place in a two-step process: barrierless cage opening followed by Coulomb repulsion-driven fragmentation.</p>}},
author = {{Maclot, Sylvain and Lahl, Jan and Peschel, Jasper and Wikmark, Hampus and Rudawski, Piotr and Brunner, Fabian and Coudert-Alteirac, Hélène and Indrajith, Suvasthika and Huber, Bernd A and Díaz-Tendero, Sergio and Aguirre, Néstor F and Rousseau, Patrick and Johnsson, Per}},
issn = {{2045-2322}},
language = {{eng}},
month = {{02}},
number = {{1}},
publisher = {{Nature Publishing Group}},
series = {{Scientific Reports}},
title = {{Dissociation dynamics of the diamondoid adamantane upon photoionization by XUV femtosecond pulses}},
url = {{http://dx.doi.org/10.1038/s41598-020-59649-1}},
doi = {{10.1038/s41598-020-59649-1}},
volume = {{10}},
year = {{2020}},
}