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Bridge splitting of trans-[PtCl2(C2H4)](2) by ethene using a simple combined NMR-UV/vis cell: Crystal and molecular structure of cis-[PtCl2(C2H4)(2)]

Otto, Stefanus ; Roodt, Andreas and Elding, Lars Ivar LU (2006) In Inorganic Chemistry Communications 9(7). p.764-766
Abstract
Bridge splitting of trans- [PtCl2(C2H4)](2) by C2H4 in chloroform yields trans-[PtCl2(C2H4)(2)] which slowly isomerises to cis[PtCl2(C2H4)(2)] (crystal structure reported); the bridge-splitting equilibrium constant was determined as 6.8 +/- 0.6 mol(-1) dm(3) by the use of a combined NMR tube/spectrophotometric cell, enabling NMR and UV/vis measurements on the same closed system. (C) 2006 Elsevier B.V. All rights reserved.
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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
combined UV/vis NMR, bridge-splitting, ethene, platinum(II)
in
Inorganic Chemistry Communications
volume
9
issue
7
pages
764 - 766
publisher
Elsevier
external identifiers
  • wos:000238718300025
  • scopus:33744985538
ISSN
1879-0259
DOI
10.1016/j.inoche.2006.04.006
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Inorganic chemistry (ceased) (LUR000010)
id
6554495f-71c2-48a8-86e9-2557c3c75e55 (old id 404537)
date added to LUP
2016-04-01 12:04:15
date last changed
2025-10-14 09:34:47
@article{6554495f-71c2-48a8-86e9-2557c3c75e55,
  abstract     = {{Bridge splitting of trans- [PtCl2(C2H4)](2) by C2H4 in chloroform yields trans-[PtCl2(C2H4)(2)] which slowly isomerises to cis[PtCl2(C2H4)(2)] (crystal structure reported); the bridge-splitting equilibrium constant was determined as 6.8 +/- 0.6 mol(-1) dm(3) by the use of a combined NMR tube/spectrophotometric cell, enabling NMR and UV/vis measurements on the same closed system. (C) 2006 Elsevier B.V. All rights reserved.}},
  author       = {{Otto, Stefanus and Roodt, Andreas and Elding, Lars Ivar}},
  issn         = {{1879-0259}},
  keywords     = {{combined UV/vis NMR; bridge-splitting; ethene; platinum(II)}},
  language     = {{eng}},
  number       = {{7}},
  pages        = {{764--766}},
  publisher    = {{Elsevier}},
  series       = {{Inorganic Chemistry Communications}},
  title        = {{Bridge splitting of trans-[PtCl2(C2H4)](2) by ethene using a simple combined NMR-UV/vis cell: Crystal and molecular structure of cis-[PtCl2(C2H4)(2)]}},
  url          = {{http://dx.doi.org/10.1016/j.inoche.2006.04.006}},
  doi          = {{10.1016/j.inoche.2006.04.006}},
  volume       = {{9}},
  year         = {{2006}},
}