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Bis{μ-cis-1,3-bis-[(di-tert-butyl-phosphan-yl)-oxy]cyclo-hexane-κ(2) P:P'}bis-[carbonylnickel(0)] including an unknown solvent molecule.

Jonasson, Klara LU and Wendt, Ola LU (2014) In Acta Crystallographica Section E: Structure Reports Online 70(Pt 5). p.176-177
Abstract
The title compound, [Ni2(C22H46P2O2)2(CO)2], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal-planar geometry. The cyclo-hexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific inter-molecular inter-actions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. Its formula mass and unit-cell characteristics were not taken into account during refinement.
Please use this url to cite or link to this publication:
author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
70
issue
Pt 5
pages
176 - 177
publisher
International Union of Crystallography
external identifiers
  • pmid:24860309
  • scopus:84899954551
  • pmid:24860309
ISSN
1600-5368
DOI
10.1107/S1600536814007818
language
English
LU publication?
yes
id
39779280-7209-4089-a15b-6af95b613ea1 (old id 4452575)
date added to LUP
2016-04-01 14:48:43
date last changed
2022-01-28 02:36:53
@article{39779280-7209-4089-a15b-6af95b613ea1,
  abstract     = {{The title compound, [Ni2(C22H46P2O2)2(CO)2], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal-planar geometry. The cyclo-hexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific inter-molecular inter-actions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. Its formula mass and unit-cell characteristics were not taken into account during refinement.}},
  author       = {{Jonasson, Klara and Wendt, Ola}},
  issn         = {{1600-5368}},
  language     = {{eng}},
  number       = {{Pt 5}},
  pages        = {{176--177}},
  publisher    = {{International Union of Crystallography}},
  series       = {{Acta Crystallographica Section E: Structure Reports Online}},
  title        = {{Bis{μ-cis-1,3-bis-[(di-tert-butyl-phosphan-yl)-oxy]cyclo-hexane-κ(2) P:P'}bis-[carbonylnickel(0)] including an unknown solvent molecule.}},
  url          = {{http://dx.doi.org/10.1107/S1600536814007818}},
  doi          = {{10.1107/S1600536814007818}},
  volume       = {{70}},
  year         = {{2014}},
}