Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapods
(2018) In Nanoscale p.18153-18160- Abstract
- The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy2ScN@C80 single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and ab initio calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by ab initio calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically... (More)
- The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy2ScN@C80 single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and ab initio calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by ab initio calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy2ScN@C80 SMMs compared to the bulk analog. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/52b2b02b-85dc-428f-bd23-5128205e1919
- author
- Avdoshenko, S. M. ; Fritz, Fabian ; Schlesier, Christin ; Kostanyan, Aram ; Dreiser, Jan ; Luysberg, Martina ; Popov, Alexey ; Meyer, Carola and Westerström, Rasmus LU
- organization
- publishing date
- 2018
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Nanoscale
- pages
- 18153 - 18160
- publisher
- Royal Society of Chemistry
- external identifiers
-
- scopus:85054435393
- ISSN
- 2040-3372
- DOI
- 10.1039/C8NR05386C
- language
- English
- LU publication?
- yes
- id
- 52b2b02b-85dc-428f-bd23-5128205e1919
- date added to LUP
- 2018-08-29 14:53:45
- date last changed
- 2022-04-25 08:55:48
@article{52b2b02b-85dc-428f-bd23-5128205e1919, abstract = {{The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy2ScN@C80 single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and ab initio calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by ab initio calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy2ScN@C80 SMMs compared to the bulk analog.}}, author = {{Avdoshenko, S. M. and Fritz, Fabian and Schlesier, Christin and Kostanyan, Aram and Dreiser, Jan and Luysberg, Martina and Popov, Alexey and Meyer, Carola and Westerström, Rasmus}}, issn = {{2040-3372}}, language = {{eng}}, pages = {{18153--18160}}, publisher = {{Royal Society of Chemistry}}, series = {{Nanoscale}}, title = {{Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapods}}, url = {{http://dx.doi.org/10.1039/C8NR05386C}}, doi = {{10.1039/C8NR05386C}}, year = {{2018}}, }