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Hydrothermal carbon release to the ocean and atmosphere from the eastern equatorial Pacific during the last glacial termination

Stott, Lowell D. ; Harazin, Kathleen M. and Quintana Krupinski, Nadine B. LU (2019) In Environmental Research Letters 14(2).
Abstract


Arguably among the most globally impactful climate changes in Earth's past million years are the glacial terminations that punctuated the Pleistocene epoch. With the acquisition and analysis of marine and continental records, including ice cores, it is now clear that the Earth's climate was responding profoundly to changes in greenhouse gases that accompanied those glacial terminations. But the ultimate forcing responsible for the greenhouse gas variability remains elusive. The oceans must play a central role in any hypothesis that attempt to explain the systematic variations in pCO
2
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Arguably among the most globally impactful climate changes in Earth's past million years are the glacial terminations that punctuated the Pleistocene epoch. With the acquisition and analysis of marine and continental records, including ice cores, it is now clear that the Earth's climate was responding profoundly to changes in greenhouse gases that accompanied those glacial terminations. But the ultimate forcing responsible for the greenhouse gas variability remains elusive. The oceans must play a central role in any hypothesis that attempt to explain the systematic variations in pCO
2
because the Ocean is a giant carbon capacitor, regulating carbon entering and leaving the atmosphere. For a long time, geological processes that regulate fluxes of carbon to and from the oceans were thought to operate too slowly to account for any of the systematic variations in atmospheric pCO
2
that accompanied glacial cycles during the Pleistocene. Here we investigate the role that Earth's hydrothermal systems had in affecting the flux of carbon to the ocean and ultimately, the atmosphere during the last glacial termination. We document late glacial and deglacial intervals of anomalously old
14
C reservoir ages, large benthic-planktic foraminifera
14
C age differences, and increased deposition of hydrothermal metals in marine sediments from the eastern equatorial Pacific (EEP) that indicate a significant release of hydrothermal fluids entered the ocean at the last glacial termination. The large
14
C anomaly was accompanied by a ∼4-fold increase in Zn/Ca in both benthic and planktic foraminifera that reflects an increase in dissolved [Zn] throughout the water column. Foraminiferal B/Ca and Li/Ca results from these sites document deglacial declines in [] throughout the water column; these were accompanied by carbonate dissolution at water depths that today lie well above the calcite lysocline. Taken together, these results are strong evidence for an increased flux of hydrothermally-derived carbon through the EEP upwelling system at the last glacial termination that would have exchanged with the atmosphere and affected both Δ
14
C and pCO
2
. These data do not quantify the amount of carbon released to the atmosphere through the EEP upwelling system but indicate that geologic forcing must be incorporated into models that attempt to simulate the cyclic nature of glacial/interglacial climate variability. Importantly, these results underscore the need to put better constraints on the flux of carbon from geologic reservoirs that affect the global carbon budget.

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organization
publishing date
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Contribution to journal
publication status
published
subject
keywords
glacial termination, hydrothermal carbon, pCO
in
Environmental Research Letters
volume
14
issue
2
article number
025007
publisher
IOP Publishing
external identifiers
  • scopus:85064122031
ISSN
1748-9326
DOI
10.1088/1748-9326/aafe28
language
English
LU publication?
yes
id
5b5e3273-7f19-4ce6-bbcf-c47b2687b8cf
date added to LUP
2019-05-02 11:58:59
date last changed
2022-04-25 22:51:18
@article{5b5e3273-7f19-4ce6-bbcf-c47b2687b8cf,
  abstract     = {{<p><br>
                                                         Arguably among the most globally impactful climate changes in Earth's past million years are the glacial terminations that punctuated the Pleistocene epoch. With the acquisition and analysis of marine and continental records, including ice cores, it is now clear that the Earth's climate was responding profoundly to changes in greenhouse gases that accompanied those glacial terminations. But the ultimate forcing responsible for the greenhouse gas variability remains elusive. The oceans must play a central role in any hypothesis that attempt to explain the systematic variations in pCO                             <br>
                            <sub>2</sub><br>
                                                          because the Ocean is a giant carbon capacitor, regulating carbon entering and leaving the atmosphere. For a long time, geological processes that regulate fluxes of carbon to and from the oceans were thought to operate too slowly to account for any of the systematic variations in atmospheric pCO                             <br>
                            <sub>2</sub><br>
                                                          that accompanied glacial cycles during the Pleistocene. Here we investigate the role that Earth's hydrothermal systems had in affecting the flux of carbon to the ocean and ultimately, the atmosphere during the last glacial termination. We document late glacial and deglacial intervals of anomalously old                              <br>
                            <sup>14</sup><br>
                                                         C reservoir ages, large benthic-planktic foraminifera                              <br>
                            <sup>14</sup><br>
                                                         C age differences, and increased deposition of hydrothermal metals in marine sediments from the eastern equatorial Pacific (EEP) that indicate a significant release of hydrothermal fluids entered the ocean at the last glacial termination. The large                              <br>
                            <sup>14</sup><br>
                                                         C anomaly was accompanied by a ∼4-fold increase in Zn/Ca in both benthic and planktic foraminifera that reflects an increase in dissolved [Zn] throughout the water column. Foraminiferal B/Ca and Li/Ca results from these sites document deglacial declines in [] throughout the water column; these were accompanied by carbonate dissolution at water depths that today lie well above the calcite lysocline. Taken together, these results are strong evidence for an increased flux of hydrothermally-derived carbon through the EEP upwelling system at the last glacial termination that would have exchanged with the atmosphere and affected both Δ                             <br>
                            <sup>14</sup><br>
                                                         C and pCO                             <br>
                            <sub>2</sub><br>
                                                         . These data do not quantify the amount of carbon released to the atmosphere through the EEP upwelling system but indicate that geologic forcing must be incorporated into models that attempt to simulate the cyclic nature of glacial/interglacial climate variability. Importantly, these results underscore the need to put better constraints on the flux of carbon from geologic reservoirs that affect the global carbon budget.                         <br>
                        </p>}},
  author       = {{Stott, Lowell D. and Harazin, Kathleen M. and Quintana Krupinski, Nadine B.}},
  issn         = {{1748-9326}},
  keywords     = {{glacial termination; hydrothermal carbon; pCO}},
  language     = {{eng}},
  month        = {{02}},
  number       = {{2}},
  publisher    = {{IOP Publishing}},
  series       = {{Environmental Research Letters}},
  title        = {{Hydrothermal carbon release to the ocean and atmosphere from the eastern equatorial Pacific during the last glacial termination}},
  url          = {{http://dx.doi.org/10.1088/1748-9326/aafe28}},
  doi          = {{10.1088/1748-9326/aafe28}},
  volume       = {{14}},
  year         = {{2019}},
}