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On sorption hysteresis in wood : Separating hysteresis in cell wall water and capillary water in the full moisture range

Fredriksson, Maria LU orcid and Engelund Thybring, Emil (2019) In PLoS ONE 14(11).
Abstract
Moisture influences most physical wood properties and plays an important role in degradation processes. Like most other porous materials, wood exhibits sorption hysteresis. That is, the moisture content is higher if equilibrium is reached by desorption than if it is reached by absorption under the same ambient climate conditions. The mechanism of moisture uptake by wood are different in the hygroscopic and over-hygroscopic moisture ranges and due to methodical issues, most studies of sorption hysteresis have been performed in the hygroscopic range. In the present study, total sorption hysteresis was separated into hysteresis in cell wall water and capillary water respectively in the whole moisture range by a novel combination of... (More)
Moisture influences most physical wood properties and plays an important role in degradation processes. Like most other porous materials, wood exhibits sorption hysteresis. That is, the moisture content is higher if equilibrium is reached by desorption than if it is reached by absorption under the same ambient climate conditions. The mechanism of moisture uptake by wood are different in the hygroscopic and over-hygroscopic moisture ranges and due to methodical issues, most studies of sorption hysteresis have been performed in the hygroscopic range. In the present study, total sorption hysteresis was separated into hysteresis in cell wall water and capillary water respectively in the whole moisture range by a novel combination of experimental techniques. Wood specimens were conditioned to several high moisture contents using a new system based on the pressure plate technique, and the distinction between cell wall water and capillary water was done with differential scanning calorimetry. The results showed that sorption hysteresis in wood cell walls exists in the whole moisture range. The cell walls were not saturated with water until the whole wood specimen was saturated which contradicts the long-held dogma that cell walls are saturated before significant amounts of capillary water are present in wood. (Less)
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author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
PLoS ONE
volume
14
issue
11
article number
e0225111
pages
16 pages
publisher
Public Library of Science (PLoS)
external identifiers
  • scopus:85075068069
  • pmid:31730652
ISSN
1932-6203
DOI
10.1371/journal.pone.0225111
project
Fundamental understanding of the moisture uptake in modified wood for sustainable, durable wood structures
language
English
LU publication?
yes
id
5c3887cb-f31b-4d17-97bc-45dc531820cf
date added to LUP
2019-11-18 09:05:22
date last changed
2022-11-07 07:02:50
@article{5c3887cb-f31b-4d17-97bc-45dc531820cf,
  abstract     = {{Moisture influences most physical wood properties and plays an important role in degradation processes. Like most other porous materials, wood exhibits sorption hysteresis. That is, the moisture content is higher if equilibrium is reached by desorption than if it is reached by absorption under the same ambient climate conditions. The mechanism of moisture uptake by wood are different in the hygroscopic and over-hygroscopic moisture ranges and due to methodical issues, most studies of sorption hysteresis have been performed in the hygroscopic range. In the present study, total sorption hysteresis was separated into hysteresis in cell wall water and capillary water respectively in the whole moisture range by a novel combination of experimental techniques. Wood specimens were conditioned to several high moisture contents using a new system based on the pressure plate technique, and the distinction between cell wall water and capillary water was done with differential scanning calorimetry. The results showed that sorption hysteresis in wood cell walls exists in the whole moisture range. The cell walls were not saturated with water until the whole wood specimen was saturated which contradicts the long-held dogma that cell walls are saturated before significant amounts of capillary water are present in wood.}},
  author       = {{Fredriksson, Maria and Engelund Thybring, Emil}},
  issn         = {{1932-6203}},
  language     = {{eng}},
  month        = {{11}},
  number       = {{11}},
  publisher    = {{Public Library of Science (PLoS)}},
  series       = {{PLoS ONE}},
  title        = {{On sorption hysteresis in wood : Separating hysteresis in cell wall water and capillary water in the full moisture range}},
  url          = {{http://dx.doi.org/10.1371/journal.pone.0225111}},
  doi          = {{10.1371/journal.pone.0225111}},
  volume       = {{14}},
  year         = {{2019}},
}