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Defect guided conduction in graphene-derivatives and MoS2 : Two-dimensional nanomaterial models

Debbarma, Rousan LU ; Nguyen, Ngoc Hoang Lan and Berry, Vikas (2021) In Applied Materials Today 23.
Abstract

The realization of unique scientific phenomena in two-dimensional nanomaterials (2DNMs) has led to their applications in several electronic fields; making it imperative to understand the conduction mechanism of charge carriers in such systems. Though several studies have been conducted on 2DNMs with pristine crystallinity, the inevitable presence of defects in the crystals requires careful consideration of their effect on 2DNMs’ electrical behavior. Here, we outline the effects of chemical, structural, substrate-induced defects and disorder on the conduction mechanism within 2DNMs, particularly graphene derivatives and MoS2. The conduction mechanisms discussed in this work are thermally activated conduction, nearest neighbor... (More)

The realization of unique scientific phenomena in two-dimensional nanomaterials (2DNMs) has led to their applications in several electronic fields; making it imperative to understand the conduction mechanism of charge carriers in such systems. Though several studies have been conducted on 2DNMs with pristine crystallinity, the inevitable presence of defects in the crystals requires careful consideration of their effect on 2DNMs’ electrical behavior. Here, we outline the effects of chemical, structural, substrate-induced defects and disorder on the conduction mechanism within 2DNMs, particularly graphene derivatives and MoS2. The conduction mechanisms discussed in this work are thermally activated conduction, nearest neighbor hopping, Efros-Shklovskii variable range hopping, and Mott variable range hopping. This review will be beneficial to the various material scientists studying the electronic properties of two-dimensional nanomaterials.

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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
2D materials, Conduction mechanism, Defects, Hopping, Localization
in
Applied Materials Today
volume
23
article number
101072
publisher
Elsevier
external identifiers
  • scopus:85110436219
ISSN
2352-9407
DOI
10.1016/j.apmt.2021.101072
language
English
LU publication?
yes
id
5df62fad-7318-48f9-871a-615dfbf03d62
date added to LUP
2021-08-23 11:11:02
date last changed
2023-11-08 17:51:46
@article{5df62fad-7318-48f9-871a-615dfbf03d62,
  abstract     = {{<p>The realization of unique scientific phenomena in two-dimensional nanomaterials (2DNMs) has led to their applications in several electronic fields; making it imperative to understand the conduction mechanism of charge carriers in such systems. Though several studies have been conducted on 2DNMs with pristine crystallinity, the inevitable presence of defects in the crystals requires careful consideration of their effect on 2DNMs’ electrical behavior. Here, we outline the effects of chemical, structural, substrate-induced defects and disorder on the conduction mechanism within 2DNMs, particularly graphene derivatives and MoS<sub>2</sub>. The conduction mechanisms discussed in this work are thermally activated conduction, nearest neighbor hopping, Efros-Shklovskii variable range hopping, and Mott variable range hopping. This review will be beneficial to the various material scientists studying the electronic properties of two-dimensional nanomaterials.</p>}},
  author       = {{Debbarma, Rousan and Nguyen, Ngoc Hoang Lan and Berry, Vikas}},
  issn         = {{2352-9407}},
  keywords     = {{2D materials; Conduction mechanism; Defects; Hopping; Localization}},
  language     = {{eng}},
  publisher    = {{Elsevier}},
  series       = {{Applied Materials Today}},
  title        = {{Defect guided conduction in graphene-derivatives and MoS<sub>2</sub> : Two-dimensional nanomaterial models}},
  url          = {{http://dx.doi.org/10.1016/j.apmt.2021.101072}},
  doi          = {{10.1016/j.apmt.2021.101072}},
  volume       = {{23}},
  year         = {{2021}},
}