Driving forces behind ion-ion correlations
Lund, Mikael LU
and Jönsson, Bo
LU
(2006)
In Journal of Chemical Physics
125(23).
- Abstract
- Within the primitive model of electrolytes, partitioning the system free energy into contributions from entropy and energy requires an explicit description of the temperature dependence of the dielectric constant epsilonr. Taking this into account, the authors find that the ion-ion correlation attraction between like charged macroions is governed by entropy and not energy as often argued. The authors have exemplified this via Monte Carlo simulations and show how [partial-derivative]epsilonr/[partial-derivative]T turns the “traditional” picture upside down.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/677344
- author
- Lund, Mikael
LU
and Jönsson, Bo
LU
- organization
- publishing date
- 2006
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 125
- issue
- 23
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000243415300039
- scopus:33845734987
- ISSN
- 0021-9606
- DOI
- 10.1063/1.2403878
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039)
- id
- 4df300eb-e35a-4dc3-abc7-314024521536 (old id 677344)
- date added to LUP
- 2016-04-01 12:24:55
- date last changed
- 2023-01-03 08:13:33
@article{4df300eb-e35a-4dc3-abc7-314024521536,
abstract = {{Within the primitive model of electrolytes, partitioning the system free energy into contributions from entropy and energy requires an explicit description of the temperature dependence of the dielectric constant epsilonr. Taking this into account, the authors find that the ion-ion correlation attraction between like charged macroions is governed by entropy and not energy as often argued. The authors have exemplified this via Monte Carlo simulations and show how [partial-derivative]epsilonr/[partial-derivative]T turns the “traditional” picture upside down.}},
author = {{Lund, Mikael and Jönsson, Bo}},
issn = {{0021-9606}},
language = {{eng}},
number = {{23}},
publisher = {{American Institute of Physics (AIP)}},
series = {{Journal of Chemical Physics}},
title = {{Driving forces behind ion-ion correlations}},
url = {{http://dx.doi.org/10.1063/1.2403878}},
doi = {{10.1063/1.2403878}},
volume = {{125}},
year = {{2006}},
}