Methane dynamics in the 36 Å mesopores of MCM-41 studied by neutron scattering
Edler, K. J. LU
; Reynolds, P. A.
; Trouw, F.
and White, J. W.
(1996)
In Chemical Physics Letters
249(5-6).
p.438-443
- Abstract
The capillary melting of methane adsorbed into the uniform parallel mesopores of the new silicate MCM-41 has been studied by neutron inelastic scattering and neutron quasielastic scattering at an energy resolution of about 80 microelectron volts. Differences from bulk methane in both the rotational melting and the solid to liquid transition have been identified. Rotational melting occurs at about 35 K, nearly ten degrees above the onset for the bulk; translational melting starts at around 60 K, nearly 30 degrees below the melting point of bulk methane.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/6b61f331-1c76-4b16-b66e-74bda1f7fde6
- author
- Edler, K. J.
LU
; Reynolds, P. A.
; Trouw, F.
and White, J. W.
- publishing date
- 1996-02-09
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics Letters
- volume
- 249
- issue
- 5-6
- pages
- 6 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:0030576025
- ISSN
- 0009-2614
- DOI
- 10.1016/0009-2614(95)01440-3
- language
- English
- LU publication?
- no
- id
- 6b61f331-1c76-4b16-b66e-74bda1f7fde6
- date added to LUP
- 2022-07-12 15:54:59
- date last changed
- 2022-07-26 14:16:44
@article{6b61f331-1c76-4b16-b66e-74bda1f7fde6,
abstract = {{<p>The capillary melting of methane adsorbed into the uniform parallel mesopores of the new silicate MCM-41 has been studied by neutron inelastic scattering and neutron quasielastic scattering at an energy resolution of about 80 microelectron volts. Differences from bulk methane in both the rotational melting and the solid to liquid transition have been identified. Rotational melting occurs at about 35 K, nearly ten degrees above the onset for the bulk; translational melting starts at around 60 K, nearly 30 degrees below the melting point of bulk methane.</p>}},
author = {{Edler, K. J. and Reynolds, P. A. and Trouw, F. and White, J. W.}},
issn = {{0009-2614}},
language = {{eng}},
month = {{02}},
number = {{5-6}},
pages = {{438--443}},
publisher = {{Elsevier}},
series = {{Chemical Physics Letters}},
title = {{Methane dynamics in the 36 Å mesopores of MCM-41 studied by neutron scattering}},
url = {{http://dx.doi.org/10.1016/0009-2614(95)01440-3}},
doi = {{10.1016/0009-2614(95)01440-3}},
volume = {{249}},
year = {{1996}},
}