Iridium complexes with aliphatic, non-innocent pincer ligands
(2018) In Journal of Organometallic Chemistry 867. p.33-50- Abstract
Pincer complexes attract considerable attention both as interesting objects for fundamental studies and efficient catalysts. This review describes a relatively new offshoot of the field - namely, the chemistry of iridium complexes with aliphatic PCsp3P non-innocent pincer ligands. High flexibility, often combined with possibility to activate internal C-H bonds, offers several new patterns of metal-ligand cooperation; some of them were successfully used in catalysis of acceptorless alcohol dehydrogenation, olefin hydroformylation and deuterium exchange, others opened up for remarkable stoichiometric reactions.
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https://lup.lub.lu.se/record/6e76388b-07bc-4a6a-8d4a-1b7af4aa0a60
- author
- Polukeev, Alexey V. LU and Wendt, Ola F. LU
- organization
- publishing date
- 2018
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Catalysis, Iridium, Metal-ligand cooperation, Non-innocent ligands, Pincer complexes
- in
- Journal of Organometallic Chemistry
- volume
- 867
- pages
- 33 - 50
- publisher
- Elsevier
- external identifiers
-
- scopus:85038819939
- ISSN
- 0022-328X
- DOI
- 10.1016/j.jorganchem.2017.12.009
- language
- English
- LU publication?
- yes
- id
- 6e76388b-07bc-4a6a-8d4a-1b7af4aa0a60
- date added to LUP
- 2018-01-04 13:37:53
- date last changed
- 2022-03-17 03:26:24
@article{6e76388b-07bc-4a6a-8d4a-1b7af4aa0a60, abstract = {{<p>Pincer complexes attract considerable attention both as interesting objects for fundamental studies and efficient catalysts. This review describes a relatively new offshoot of the field - namely, the chemistry of iridium complexes with aliphatic PC<sub>sp3</sub>P non-innocent pincer ligands. High flexibility, often combined with possibility to activate internal C-H bonds, offers several new patterns of metal-ligand cooperation; some of them were successfully used in catalysis of acceptorless alcohol dehydrogenation, olefin hydroformylation and deuterium exchange, others opened up for remarkable stoichiometric reactions.</p>}}, author = {{Polukeev, Alexey V. and Wendt, Ola F.}}, issn = {{0022-328X}}, keywords = {{Catalysis; Iridium; Metal-ligand cooperation; Non-innocent ligands; Pincer complexes}}, language = {{eng}}, pages = {{33--50}}, publisher = {{Elsevier}}, series = {{Journal of Organometallic Chemistry}}, title = {{Iridium complexes with aliphatic, non-innocent pincer ligands}}, url = {{http://dx.doi.org/10.1016/j.jorganchem.2017.12.009}}, doi = {{10.1016/j.jorganchem.2017.12.009}}, volume = {{867}}, year = {{2018}}, }