Cyclometallated phenyl-pyridine palladium species. Monomeric complex formation with potentially bridging ligands
(2016) In Inorganica Chimica Acta 443. p.136-140- Abstract
- The cyclometallated dinuclear (2-phenyl-pyridine) palladium acetate and chloride [{PdCl(phpy)}(2)] and [{PdOAc(phpy)}(2)] were reacted with potentially bridging N- and S-donor ligands. The N,N-ligands bind with only one nitrogen and form monomeric products. The S,S-ligand binds in a chelate mode, also forming a monomeric complex. 3,3-Dimethyl glutarate, on the other hand, binds in a bridging mode. An X-ray structure of the complex with naphthyridine is presented. (C) 2016 Elsevier B.V. All rights reserved.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/8728510
- author
- Kondrashov, Mikhail LU ; Gritcenko, Roman ; Fleckhaus, André LU and Wendt, Ola LU
- organization
- publishing date
- 2016
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Palladium, Bidentate ligands, Bridging ligands, C-H activation
- in
- Inorganica Chimica Acta
- volume
- 443
- pages
- 136 - 140
- publisher
- Elsevier
- external identifiers
-
- wos:000369070900019
- scopus:84953911213
- ISSN
- 0020-1693
- DOI
- 10.1016/j.ica.2015.12.032
- language
- English
- LU publication?
- yes
- id
- dac125e1-d8cd-4d37-9f96-db728aad61e4 (old id 8728510)
- date added to LUP
- 2016-04-01 12:57:22
- date last changed
- 2022-01-27 08:29:23
@article{dac125e1-d8cd-4d37-9f96-db728aad61e4, abstract = {{The cyclometallated dinuclear (2-phenyl-pyridine) palladium acetate and chloride [{PdCl(phpy)}(2)] and [{PdOAc(phpy)}(2)] were reacted with potentially bridging N- and S-donor ligands. The N,N-ligands bind with only one nitrogen and form monomeric products. The S,S-ligand binds in a chelate mode, also forming a monomeric complex. 3,3-Dimethyl glutarate, on the other hand, binds in a bridging mode. An X-ray structure of the complex with naphthyridine is presented. (C) 2016 Elsevier B.V. All rights reserved.}}, author = {{Kondrashov, Mikhail and Gritcenko, Roman and Fleckhaus, André and Wendt, Ola}}, issn = {{0020-1693}}, keywords = {{Palladium; Bidentate ligands; Bridging ligands; C-H activation}}, language = {{eng}}, pages = {{136--140}}, publisher = {{Elsevier}}, series = {{Inorganica Chimica Acta}}, title = {{Cyclometallated phenyl-pyridine palladium species. Monomeric complex formation with potentially bridging ligands}}, url = {{http://dx.doi.org/10.1016/j.ica.2015.12.032}}, doi = {{10.1016/j.ica.2015.12.032}}, volume = {{443}}, year = {{2016}}, }