Macroscopic Domains within an Oriented TQ1 Film Visualized Using 2D Polarization Imaging
Täuber, Daniela LU ; Cai, Wanzhu ; Inganäs, Olle and Scheblykin, Ivan G. LU
(2017)
In ACS Omega
2(1).
p.32-40
- Abstract
Large-area self-assembly of functional conjugated polymers holds a great potential for practical applications of organic electronic devices. We obtained well-aligned films of poly[2,3-bis(3-octyloxyphenyl)quinoxaline-5,8-diyl-alt-thiophene-2,5-diyl] (TQ1) using the floating film transfer method. Thereby, a droplet of the TQ1 solution was injected on top of the surface of an immiscible liquid substrate, at the meniscus formed at the edge of a Petri dish, from where the polymer solution and the film spread in one direction. Characterization of the TQ1 film using the recently developed two-dimensional polarization imaging (2D POLIM) revealed large, millimeter-sized domains of oriented polymer chains. The irregular shape of the contact line... (More)
Large-area self-assembly of functional conjugated polymers holds a great potential for practical applications of organic electronic devices. We obtained well-aligned films of poly[2,3-bis(3-octyloxyphenyl)quinoxaline-5,8-diyl-alt-thiophene-2,5-diyl] (TQ1) using the floating film transfer method. Thereby, a droplet of the TQ1 solution was injected on top of the surface of an immiscible liquid substrate, at the meniscus formed at the edge of a Petri dish, from where the polymer solution and the film spread in one direction. Characterization of the TQ1 film using the recently developed two-dimensional polarization imaging (2D POLIM) revealed large, millimeter-sized domains of oriented polymer chains. The irregular shape of the contact line at the droplet source induced the appearance of disordered stripes perpendicular to the spreading direction. A correlation of polarization parameters measured using 2D POLIM revealed the microstructure of such stripes, providing valuable information for further improvement and possible upscaling of this promising method.
(Less)
- author
- Täuber, Daniela
LU
; Cai, Wanzhu
; Inganäs, Olle
and Scheblykin, Ivan G.
LU
- organization
- publishing date
- 2017-01-31
- type
- Contribution to journal
- publication status
- published
- subject
- in
- ACS Omega
- volume
- 2
- issue
- 1
- pages
- 9 pages
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- scopus:85028920695
- wos:000395862400004
- ISSN
- 2470-1343
- DOI
- 10.1021/acsomega.6b00264
- language
- English
- LU publication?
- yes
- id
- f2174fe5-74d5-4666-bc4e-39cc6a48cbfc
- date added to LUP
- 2017-09-27 13:24:39
- date last changed
- 2024-10-14 13:42:38
@article{f2174fe5-74d5-4666-bc4e-39cc6a48cbfc,
abstract = {{<p>Large-area self-assembly of functional conjugated polymers holds a great potential for practical applications of organic electronic devices. We obtained well-aligned films of poly[2,3-bis(3-octyloxyphenyl)quinoxaline-5,8-diyl-alt-thiophene-2,5-diyl] (TQ1) using the floating film transfer method. Thereby, a droplet of the TQ1 solution was injected on top of the surface of an immiscible liquid substrate, at the meniscus formed at the edge of a Petri dish, from where the polymer solution and the film spread in one direction. Characterization of the TQ1 film using the recently developed two-dimensional polarization imaging (2D POLIM) revealed large, millimeter-sized domains of oriented polymer chains. The irregular shape of the contact line at the droplet source induced the appearance of disordered stripes perpendicular to the spreading direction. A correlation of polarization parameters measured using 2D POLIM revealed the microstructure of such stripes, providing valuable information for further improvement and possible upscaling of this promising method.</p>}},
author = {{Täuber, Daniela and Cai, Wanzhu and Inganäs, Olle and Scheblykin, Ivan G.}},
issn = {{2470-1343}},
language = {{eng}},
month = {{01}},
number = {{1}},
pages = {{32--40}},
publisher = {{The American Chemical Society (ACS)}},
series = {{ACS Omega}},
title = {{Macroscopic Domains within an Oriented TQ1 Film Visualized Using 2D Polarization Imaging}},
url = {{http://dx.doi.org/10.1021/acsomega.6b00264}},
doi = {{10.1021/acsomega.6b00264}},
volume = {{2}},
year = {{2017}},
}