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Axial motion of water hydrogen halide and water halogen complexes in argon matrices

Engdahl, Anders LU and Nelander, Bengt LU (1986) In The Journal of chemical physics 84(4). p.1981-1987
Abstract

The infrared spectra of the water (H2O, HDO, D2O) complexes with HCl, HBr, HI Cl2, Br2, and I2 have been studied in argon matrices in the 11 to 25 K interval. In all cases, water acts as a lone-pair donor. The hydrogen halide complexes are effectively planar and rotate around the axis through the heavy atoms. For the water halogen complexes, the results are less clear, but a similar rotation, coupled to low wave number bending motions, seems possible.

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author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
The Journal of chemical physics
volume
84
issue
4
pages
7 pages
publisher
American Institute of Physics (AIP)
external identifiers
  • scopus:36549093825
ISSN
0021-9606
DOI
10.1063/1.450405
language
English
LU publication?
yes
additional info
Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
id
1119c2fd-bb15-47dd-8558-76f2719fa8e2
date added to LUP
2021-03-29 15:29:06
date last changed
2021-10-03 03:43:14
@article{1119c2fd-bb15-47dd-8558-76f2719fa8e2,
  abstract     = {{<p>The infrared spectra of the water (H<sub>2</sub>O, HDO, D<sub>2</sub>O) complexes with HCl, HBr, HI Cl<sub>2</sub>, Br<sub>2</sub>, and I<sub>2</sub> have been studied in argon matrices in the 11 to 25 K interval. In all cases, water acts as a lone-pair donor. The hydrogen halide complexes are effectively planar and rotate around the axis through the heavy atoms. For the water halogen complexes, the results are less clear, but a similar rotation, coupled to low wave number bending motions, seems possible.</p>}},
  author       = {{Engdahl, Anders and Nelander, Bengt}},
  issn         = {{0021-9606}},
  language     = {{eng}},
  month        = {{02}},
  number       = {{4}},
  pages        = {{1981--1987}},
  publisher    = {{American Institute of Physics (AIP)}},
  series       = {{The Journal of chemical physics}},
  title        = {{Axial motion of water hydrogen halide and water halogen complexes in argon matrices}},
  url          = {{http://dx.doi.org/10.1063/1.450405}},
  doi          = {{10.1063/1.450405}},
  volume       = {{84}},
  year         = {{1986}},
}