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Interaction of sodium dodecyl sulfate and high charge density comb polymers at the silica/water interface

Moglianetti, Mauro; Campbell, Richard LU ; Nylander, Tommy LU ; Varga, Imre; Mohanty, Biswarajan; Claesson, Per M.; Makuska, Ricardas and Titmuss, Simon (2009) In Soft Matter 5(19). p.3646-3656
Abstract
The structures of interfacial layers formed from mixtures of comb polymers, comprising a high charge density cationic backbone and poly(ethylene oxide) (PEO) side-chains, with the anionic surfactant sodium dodecyl sulfate (SDS) at the silica/water interface, have been determined using neutron reflectivity measurements. The use of mixtures in which only the isotopic composition of the surfactant is changed has made it possible to determine the interfacial volume fraction profiles for both the polymer and the surfactant. For the polymer with 90% of the segments charged and 10% of the segments carrying PEO side-chains, there are four regimes of interfacial behavior with increasing surfactant composition of the bulk solution. First there is... (More)
The structures of interfacial layers formed from mixtures of comb polymers, comprising a high charge density cationic backbone and poly(ethylene oxide) (PEO) side-chains, with the anionic surfactant sodium dodecyl sulfate (SDS) at the silica/water interface, have been determined using neutron reflectivity measurements. The use of mixtures in which only the isotopic composition of the surfactant is changed has made it possible to determine the interfacial volume fraction profiles for both the polymer and the surfactant. For the polymer with 90% of the segments charged and 10% of the segments carrying PEO side-chains, there are four regimes of interfacial behavior with increasing surfactant composition of the bulk solution. First there is adsorption of surfactant to the polymer-covered surface, then, slightly above polymer charge stoichiometry, there is adsorption of near-neutral polymer/surfactant complexes followed by the adsorption of polymer/surfactant aggregates, with a well-defined internal structure. If the concentration of SDS is increased directly from below polymer charge stoichiometry to above the cmc, micelles or polymer/micelle complexes interact with the pre-existing polymer layer. Increasing the fraction of segments carrying PEO side-chains to 25% suppresses the formation of charge-neutral polymer/surfactant complexes at the interface. There is an increase in the adsorption of surfactant, which interacts with the pre-existing layer of polymers. This results in the surface aggregation of SDS and a swelling of the PEO side-chains from a mushroom to a brush-like configuration. (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Soft Matter
volume
5
issue
19
pages
3646 - 3656
publisher
Royal Society of Chemistry
external identifiers
  • wos:000270117400015
  • scopus:70349323502
ISSN
1744-6848
DOI
10.1039/b905270d
language
English
LU publication?
yes
id
b92d8563-5916-4f5f-9d0d-b0d2651c5a33 (old id 1489893)
date added to LUP
2009-10-21 10:31:06
date last changed
2017-01-01 06:02:12
@article{b92d8563-5916-4f5f-9d0d-b0d2651c5a33,
  abstract     = {The structures of interfacial layers formed from mixtures of comb polymers, comprising a high charge density cationic backbone and poly(ethylene oxide) (PEO) side-chains, with the anionic surfactant sodium dodecyl sulfate (SDS) at the silica/water interface, have been determined using neutron reflectivity measurements. The use of mixtures in which only the isotopic composition of the surfactant is changed has made it possible to determine the interfacial volume fraction profiles for both the polymer and the surfactant. For the polymer with 90% of the segments charged and 10% of the segments carrying PEO side-chains, there are four regimes of interfacial behavior with increasing surfactant composition of the bulk solution. First there is adsorption of surfactant to the polymer-covered surface, then, slightly above polymer charge stoichiometry, there is adsorption of near-neutral polymer/surfactant complexes followed by the adsorption of polymer/surfactant aggregates, with a well-defined internal structure. If the concentration of SDS is increased directly from below polymer charge stoichiometry to above the cmc, micelles or polymer/micelle complexes interact with the pre-existing polymer layer. Increasing the fraction of segments carrying PEO side-chains to 25% suppresses the formation of charge-neutral polymer/surfactant complexes at the interface. There is an increase in the adsorption of surfactant, which interacts with the pre-existing layer of polymers. This results in the surface aggregation of SDS and a swelling of the PEO side-chains from a mushroom to a brush-like configuration.},
  author       = {Moglianetti, Mauro and Campbell, Richard and Nylander, Tommy and Varga, Imre and Mohanty, Biswarajan and Claesson, Per M. and Makuska, Ricardas and Titmuss, Simon},
  issn         = {1744-6848},
  language     = {eng},
  number       = {19},
  pages        = {3646--3656},
  publisher    = {Royal Society of Chemistry},
  series       = {Soft Matter},
  title        = {Interaction of sodium dodecyl sulfate and high charge density comb polymers at the silica/water interface},
  url          = {http://dx.doi.org/10.1039/b905270d},
  volume       = {5},
  year         = {2009},
}