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The gas phase reaction between CO2 and lanthanide atoms. A test of a model for the isokinetic effect

Larsson, Ragnar LU and Mascetti, J (2005) In Reaction Kinetics and Catalysis Letters 85(1). p.107-113
Abstract
Using literature data on the gas phase reaction between free lanthanide atoms and carbon dioxide, we have found an isokinetic relation for seven of the twelve investigated elements with an isokinetic temperature, T-iso of 2500 +/- 330 K. This value is analyzed in the framework of the model of selective energy transfer, SET, indicating that metal-CO2 complexes are formed as pre-reaction states. The result is in accordance with the fundamental concepts of SET.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Reaction Kinetics and Catalysis Letters
volume
85
issue
1
pages
107 - 113
publisher
Springer
external identifiers
  • wos:000229721100014
  • scopus:21144445795
ISSN
1588-2837
DOI
10.1007/s11144-005-0249-7
language
English
LU publication?
yes
id
6b1b7fc8-5499-4ebf-a9af-2a45760e3c3c (old id 151680)
date added to LUP
2007-06-25 12:40:24
date last changed
2017-01-01 04:49:57
@article{6b1b7fc8-5499-4ebf-a9af-2a45760e3c3c,
  abstract     = {Using literature data on the gas phase reaction between free lanthanide atoms and carbon dioxide, we have found an isokinetic relation for seven of the twelve investigated elements with an isokinetic temperature, T-iso of 2500 +/- 330 K. This value is analyzed in the framework of the model of selective energy transfer, SET, indicating that metal-CO2 complexes are formed as pre-reaction states. The result is in accordance with the fundamental concepts of SET.},
  author       = {Larsson, Ragnar and Mascetti, J},
  issn         = {1588-2837},
  language     = {eng},
  number       = {1},
  pages        = {107--113},
  publisher    = {Springer},
  series       = {Reaction Kinetics and Catalysis Letters},
  title        = {The gas phase reaction between CO2 and lanthanide atoms. A test of a model for the isokinetic effect},
  url          = {http://dx.doi.org/10.1007/s11144-005-0249-7},
  volume       = {85},
  year         = {2005},
}