Advanced

Intermolecular vibrations of the water trimer, a matrix isolation study

Ceponkus, Justinas ; Karlström, Gunnar LU and Nelander, Bengt LU (2005) In The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory 109(35). p.7859-7864
Abstract
Infrared spectra from 25 to 4000 cm(-1) have been recorded of water (H2O, D2O and (H2O)-O-18) matrix isolated in neon, argon, and krypton matrices. Intermolecular absorption bands of different isotopologues of the water trimer and tetramer have been assigned from concentration dependencies and diffusion behavior, using the well-known mid-infrared trimer and tetramer absorption bands as measures of the trimer and tetramer concentrations. The results are compared to ab initio calculations.
Please use this url to cite or link to this publication:
author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
volume
109
issue
35
pages
7859 - 7864
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000231687100005
  • scopus:25444527928
  • pmid:16834166
ISSN
1520-5215
DOI
10.1021/jp052096v
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039), Chemical Physics (S) (011001060)
id
675606fc-5112-41c0-88e5-96493785ec3b (old id 151846)
date added to LUP
2016-04-01 16:28:30
date last changed
2020-11-10 04:13:06
@article{675606fc-5112-41c0-88e5-96493785ec3b,
  abstract     = {Infrared spectra from 25 to 4000 cm(-1) have been recorded of water (H2O, D2O and (H2O)-O-18) matrix isolated in neon, argon, and krypton matrices. Intermolecular absorption bands of different isotopologues of the water trimer and tetramer have been assigned from concentration dependencies and diffusion behavior, using the well-known mid-infrared trimer and tetramer absorption bands as measures of the trimer and tetramer concentrations. The results are compared to ab initio calculations.},
  author       = {Ceponkus, Justinas and Karlström, Gunnar and Nelander, Bengt},
  issn         = {1520-5215},
  language     = {eng},
  number       = {35},
  pages        = {7859--7864},
  publisher    = {The American Chemical Society (ACS)},
  series       = {The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory},
  title        = {Intermolecular vibrations of the water trimer, a matrix isolation study},
  url          = {http://dx.doi.org/10.1021/jp052096v},
  doi          = {10.1021/jp052096v},
  volume       = {109},
  year         = {2005},
}