Electron spectroscopy study of the initial stages of iron phthalocyanine growth on highly oriented pyrolitic graphite.
(2009) In Journal of Chemical Physics 131(21).- Abstract
- The nature of the intermolecular and substrate bonds of iron phthalocyanine adsorbed on highly oriented pyrolitic graphite has been investigated by x-ray photoelectron spectroscopy and x-ray absorption spectroscopy. We find that the molecules grow in a highly ordered fashion with the molecules essentially plane-parallel to the surface in both the mono- and multilayers. The spectra obtained on both types of film are virtually identical, which shows that the bonds both between the adsorbate and substrate and between the molecular layers have a pure van der Waals nature. Supporting density functional theory results indicate that the layers are stabilized by weak hydrogen bonds within the molecular layers.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1523843
- author
- Isvoranu, Cristina LU ; Ahlund, John ; Wang, Bin ; Ataman, Evren LU ; Mårtensson, Nils LU ; Puglia, Carla ; Andersen, Jesper N LU ; Bocquet, Marie-Laure and Schnadt, Joachim LU
- organization
- publishing date
- 2009
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 131
- issue
- 21
- article number
- 214709
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000272494300034
- pmid:19968362
- scopus:72049100704
- ISSN
- 0021-9606
- DOI
- 10.1063/1.3259699
- language
- English
- LU publication?
- yes
- id
- 0b5a4f6a-9d98-4db3-b846-8e8f4013b8b6 (old id 1523843)
- date added to LUP
- 2016-04-01 12:07:51
- date last changed
- 2022-02-23 02:17:21
@article{0b5a4f6a-9d98-4db3-b846-8e8f4013b8b6, abstract = {{The nature of the intermolecular and substrate bonds of iron phthalocyanine adsorbed on highly oriented pyrolitic graphite has been investigated by x-ray photoelectron spectroscopy and x-ray absorption spectroscopy. We find that the molecules grow in a highly ordered fashion with the molecules essentially plane-parallel to the surface in both the mono- and multilayers. The spectra obtained on both types of film are virtually identical, which shows that the bonds both between the adsorbate and substrate and between the molecular layers have a pure van der Waals nature. Supporting density functional theory results indicate that the layers are stabilized by weak hydrogen bonds within the molecular layers.}}, author = {{Isvoranu, Cristina and Ahlund, John and Wang, Bin and Ataman, Evren and Mårtensson, Nils and Puglia, Carla and Andersen, Jesper N and Bocquet, Marie-Laure and Schnadt, Joachim}}, issn = {{0021-9606}}, language = {{eng}}, number = {{21}}, publisher = {{American Institute of Physics (AIP)}}, series = {{Journal of Chemical Physics}}, title = {{Electron spectroscopy study of the initial stages of iron phthalocyanine growth on highly oriented pyrolitic graphite.}}, url = {{http://dx.doi.org/10.1063/1.3259699}}, doi = {{10.1063/1.3259699}}, volume = {{131}}, year = {{2009}}, }