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Matrix infrared spectra and electronic structure calculations of the first actinide borylene: FB=ThF2

Wang, Xuefeng; Roos, Björn LU and Andrews, Lester (2010) In Chemical Communications 46(10). p.1646-1648
Abstract
Laser-ablated Th atoms react with BF3 during condensation in excess argon at 6 K to form the first actinide borylene (FB=ThF2) and actinide-boron multiple bond. Three new product absorptions in the B-F and Th-F stretching regions of matrix infrared spectra are assigned to FB=ThF2 from comparison to theoretically predicted vibrational frequencies.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Communications
volume
46
issue
10
pages
1646 - 1648
publisher
Royal Society of Chemistry
external identifiers
  • wos:000274827000013
  • scopus:77249157005
ISSN
1364-548X
DOI
10.1039/b923195a
language
English
LU publication?
yes
id
442cb472-9505-47ef-902b-b333ff0ad94a (old id 1568306)
date added to LUP
2010-03-23 13:17:24
date last changed
2018-05-29 12:17:33
@article{442cb472-9505-47ef-902b-b333ff0ad94a,
  abstract     = {Laser-ablated Th atoms react with BF3 during condensation in excess argon at 6 K to form the first actinide borylene (FB=ThF2) and actinide-boron multiple bond. Three new product absorptions in the B-F and Th-F stretching regions of matrix infrared spectra are assigned to FB=ThF2 from comparison to theoretically predicted vibrational frequencies.},
  author       = {Wang, Xuefeng and Roos, Björn and Andrews, Lester},
  issn         = {1364-548X},
  language     = {eng},
  number       = {10},
  pages        = {1646--1648},
  publisher    = {Royal Society of Chemistry},
  series       = {Chemical Communications},
  title        = {Matrix infrared spectra and electronic structure calculations of the first actinide borylene: FB=ThF2},
  url          = {http://dx.doi.org/10.1039/b923195a},
  volume       = {46},
  year         = {2010},
}