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Hexakis(tetraaquasodium) decavanadate(V) dihydrate

Nilsson, Jessica LU ; Nordlander, Ebbe LU ; Behrens, Ulrich and Rehder, Dieter (2010) In Acta Crystallographica Section E: Structure Reports Online 66. p.30-148
Abstract
The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
66
pages
30 - 148
publisher
Wiley-Blackwell
external identifiers
  • wos:000276190700004
  • scopus:77951236065
ISSN
1600-5368
DOI
10.1107/S1600536810010251
language
English
LU publication?
yes
id
64a56dff-4d55-4a55-921f-ff7f2516fc68 (old id 1587189)
date added to LUP
2010-04-27 09:18:53
date last changed
2018-05-29 09:22:29
@article{64a56dff-4d55-4a55-921f-ff7f2516fc68,
  abstract     = {The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.},
  author       = {Nilsson, Jessica and Nordlander, Ebbe and Behrens, Ulrich and Rehder, Dieter},
  issn         = {1600-5368},
  language     = {eng},
  pages        = {30--148},
  publisher    = {Wiley-Blackwell},
  series       = {Acta Crystallographica Section E: Structure Reports Online},
  title        = {Hexakis(tetraaquasodium) decavanadate(V) dihydrate},
  url          = {http://dx.doi.org/10.1107/S1600536810010251},
  volume       = {66},
  year         = {2010},
}