Photofragmentation of cyanogen upon carbon and nitrogen K-shell excitation by partial ion yield experiments
Öhrwall, Gunnar LU
; Stolte, W. C.
; Guillemin, R.
; Yu, S-W
; Piancastelli, M. N.
and Lindle, D. W.
(2010)
In Journal of Physics B: Atomic, Molecular and Optical Physics
43(9).
- Abstract
- Partial ion yield spectroscopy was used to study fragmentation processes in cyanogen after C 1s and N 1s photoexcitation. The interpretation of the core excitation spectrum mostly follows the literature, but the high resolution has in some cases allowed a more detailed assignment. Using the fact that in Rydberg states there is an intensity increase as the fragmentation process becomes more extensive compared to valence orbitals, we have been able to distinguish resonances with valence and Rydberg character. Furthermore, we have been able to assign features in the ionization continuum as arising from double excitations or shape resonances, by observation of the suppression of anion yield at shape resonances.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1619376
- author
- Öhrwall, Gunnar
LU
; Stolte, W. C.
; Guillemin, R.
; Yu, S-W
; Piancastelli, M. N.
and Lindle, D. W.
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Physics B: Atomic, Molecular and Optical Physics
- volume
- 43
- issue
- 9
- publisher
- IOP Publishing
- external identifiers
-
- wos:000277077100008
- scopus:77951639630
- ISSN
- 0953-4075
- DOI
- 10.1088/0953-4075/43/9/095201
- language
- English
- LU publication?
- yes
- id
- 9dad27e3-c110-4364-ab91-e930182ef358 (old id 1619376)
- date added to LUP
- 2016-04-01 14:37:13
- date last changed
- 2022-01-28 01:36:04
@article{9dad27e3-c110-4364-ab91-e930182ef358,
abstract = {{Partial ion yield spectroscopy was used to study fragmentation processes in cyanogen after C 1s and N 1s photoexcitation. The interpretation of the core excitation spectrum mostly follows the literature, but the high resolution has in some cases allowed a more detailed assignment. Using the fact that in Rydberg states there is an intensity increase as the fragmentation process becomes more extensive compared to valence orbitals, we have been able to distinguish resonances with valence and Rydberg character. Furthermore, we have been able to assign features in the ionization continuum as arising from double excitations or shape resonances, by observation of the suppression of anion yield at shape resonances.}},
author = {{Öhrwall, Gunnar and Stolte, W. C. and Guillemin, R. and Yu, S-W and Piancastelli, M. N. and Lindle, D. W.}},
issn = {{0953-4075}},
language = {{eng}},
number = {{9}},
publisher = {{IOP Publishing}},
series = {{Journal of Physics B: Atomic, Molecular and Optical Physics}},
title = {{Photofragmentation of cyanogen upon carbon and nitrogen K-shell excitation by partial ion yield experiments}},
url = {{http://dx.doi.org/10.1088/0953-4075/43/9/095201}},
doi = {{10.1088/0953-4075/43/9/095201}},
volume = {{43}},
year = {{2010}},
}