Nuclear motion in carbonyl sulfide induced by resonant core electron excitation
(2010) In Journal of Chemical Physics 133(14). p.1-144314- Abstract
- The angular anisotropy for selected dissociation channels is measured at resonantly excited states of and symmetries at the C and O K-shell ionization edges of carbonyl sulfide.
While the kinetic energy released in the reaction is mainly independent of the excitation energy, the angular anisotropy and momentum correlation clearly show deformation of the OCS molecule in the C1s−Pi state.
The discovery of a two-body fragmentation channel SO+/C+ with a well defined angular anisotropy indicates the rapid formation of the CSO isomeric species.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1692601
- author
- Laksman, Joakim LU ; Céolin, Denis LU ; Gisselbrecht, Mathieu LU and Ristinmaa Sörensen, Stacey LU
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- OCS
- in
- Journal of Chemical Physics
- volume
- 133
- issue
- 14
- pages
- 1 - 144314
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000283200400030
- scopus:77958111330
- pmid:20950007
- ISSN
- 0021-9606
- DOI
- 10.1063/1.3502116
- language
- English
- LU publication?
- yes
- id
- ceef525a-dc23-476b-860d-797a0bb7de3a (old id 1692601)
- date added to LUP
- 2016-04-01 09:58:02
- date last changed
- 2024-06-04 15:05:05
@article{ceef525a-dc23-476b-860d-797a0bb7de3a, abstract = {{The angular anisotropy for selected dissociation channels is measured at resonantly excited states of and symmetries at the C and O K-shell ionization edges of carbonyl sulfide.<br/><br> While the kinetic energy released in the reaction is mainly independent of the excitation energy, the angular anisotropy and momentum correlation clearly show deformation of the OCS molecule in the C1s−Pi state.<br/><br> The discovery of a two-body fragmentation channel SO+/C+ with a well defined angular anisotropy indicates the rapid formation of the CSO isomeric species.}}, author = {{Laksman, Joakim and Céolin, Denis and Gisselbrecht, Mathieu and Ristinmaa Sörensen, Stacey}}, issn = {{0021-9606}}, keywords = {{OCS}}, language = {{eng}}, number = {{14}}, pages = {{1--144314}}, publisher = {{American Institute of Physics (AIP)}}, series = {{Journal of Chemical Physics}}, title = {{Nuclear motion in carbonyl sulfide induced by resonant core electron excitation}}, url = {{https://lup.lub.lu.se/search/files/1432281/1692602.pdf}}, doi = {{10.1063/1.3502116}}, volume = {{133}}, year = {{2010}}, }