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Dual graphs realized in the compounds di-mu(3)-4-mercaptopyridine catena-di-mu(2)-iodo-di-mu(3)-iodo-mu(4)-iodo penta copper(I) and di-mu(3)-4-mercaptopyridine-di-catena-iodo-di-mu(3)-iodo tri copper(I)

Jalilian, Ehsan and Lidin, Sven LU (2010) In Journal of Solid State Chemistry 183(11). p.2656-2661
Abstract
Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group 141/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is non-bonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide. (C) 2010 Elsevier Inc. All rights reserved.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Structure, Copper(I), Iodide, Cluster
in
Journal of Solid State Chemistry
volume
183
issue
11
pages
2656 - 2661
publisher
Elsevier
external identifiers
  • wos:000284179800023
  • scopus:78049338110
ISSN
0022-4596
DOI
10.1016/j.jssc.2010.09.009
language
English
LU publication?
yes
id
ad0080b2-bc81-4f82-b7cc-0f5f470c5bf8 (old id 1753161)
date added to LUP
2010-12-29 14:50:29
date last changed
2018-05-29 10:42:25
@article{ad0080b2-bc81-4f82-b7cc-0f5f470c5bf8,
  abstract     = {Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group 141/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is non-bonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide. (C) 2010 Elsevier Inc. All rights reserved.},
  author       = {Jalilian, Ehsan and Lidin, Sven},
  issn         = {0022-4596},
  keyword      = {Structure,Copper(I),Iodide,Cluster},
  language     = {eng},
  number       = {11},
  pages        = {2656--2661},
  publisher    = {Elsevier},
  series       = {Journal of Solid State Chemistry},
  title        = {Dual graphs realized in the compounds di-mu(3)-4-mercaptopyridine catena-di-mu(2)-iodo-di-mu(3)-iodo-mu(4)-iodo penta copper(I) and di-mu(3)-4-mercaptopyridine-di-catena-iodo-di-mu(3)-iodo tri copper(I)},
  url          = {http://dx.doi.org/10.1016/j.jssc.2010.09.009},
  volume       = {183},
  year         = {2010},
}