Tuning the spin state of iron phthalocyanine by ligand adsorption
Isvoranu, Cristina LU ; Wang, B. ; Schulte, Karina LU ; Ataman, Evren LU ; Knudsen, Jan LU ; Andersen, Jesper N LU ; Bocquet, M. L. and Schnadt, Joachim LU
(2010)
In Journal of Physics: Condensed Matter
22(47).
- Abstract
- The future use of single-molecule magnets in applications will require the ability to control and manipulate the spin state and magnetization of the magnets by external means. There are different approaches to this control, one being the modification of the magnets by adsorption of small ligand molecules. In this paper we use iron phthalocyanine supported by an Au(111) surface as a model compound and demonstrate, using x-ray photoelectron spectroscopy and density functional theory, that the spin state of the molecule can be tuned to different values (S similar to 0, 1/2, 1) by adsorption of ammonia, pyridine, carbon monoxide or nitric oxide on the iron ion. The interaction also leads to electronic decoupling of the iron phthalocyanine from... (More)
- The future use of single-molecule magnets in applications will require the ability to control and manipulate the spin state and magnetization of the magnets by external means. There are different approaches to this control, one being the modification of the magnets by adsorption of small ligand molecules. In this paper we use iron phthalocyanine supported by an Au(111) surface as a model compound and demonstrate, using x-ray photoelectron spectroscopy and density functional theory, that the spin state of the molecule can be tuned to different values (S similar to 0, 1/2, 1) by adsorption of ammonia, pyridine, carbon monoxide or nitric oxide on the iron ion. The interaction also leads to electronic decoupling of the iron phthalocyanine from the Au(111) support. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1753174
- author
- Isvoranu, Cristina
LU
; Wang, B.
; Schulte, Karina
LU
; Ataman, Evren
LU
; Knudsen, Jan
LU
; Andersen, Jesper N
LU
; Bocquet, M. L.
and Schnadt, Joachim
LU
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Physics: Condensed Matter
- volume
- 22
- issue
- 47
- article number
- 472002
- publisher
- IOP Publishing
- external identifiers
-
- wos:000284264800015
- scopus:78649858686
- ISSN
- 1361-648X
- DOI
- 10.1088/0953-8984/22/47/472002
- language
- English
- LU publication?
- yes
- id
- ad71adec-fce0-4f9f-96dc-daf7d5606816 (old id 1753174)
- date added to LUP
- 2016-04-01 13:55:29
- date last changed
- 2023-09-03 07:06:24
@article{ad71adec-fce0-4f9f-96dc-daf7d5606816,
abstract = {{The future use of single-molecule magnets in applications will require the ability to control and manipulate the spin state and magnetization of the magnets by external means. There are different approaches to this control, one being the modification of the magnets by adsorption of small ligand molecules. In this paper we use iron phthalocyanine supported by an Au(111) surface as a model compound and demonstrate, using x-ray photoelectron spectroscopy and density functional theory, that the spin state of the molecule can be tuned to different values (S similar to 0, 1/2, 1) by adsorption of ammonia, pyridine, carbon monoxide or nitric oxide on the iron ion. The interaction also leads to electronic decoupling of the iron phthalocyanine from the Au(111) support.}},
author = {{Isvoranu, Cristina and Wang, B. and Schulte, Karina and Ataman, Evren and Knudsen, Jan and Andersen, Jesper N and Bocquet, M. L. and Schnadt, Joachim}},
issn = {{1361-648X}},
language = {{eng}},
number = {{47}},
publisher = {{IOP Publishing}},
series = {{Journal of Physics: Condensed Matter}},
title = {{Tuning the spin state of iron phthalocyanine by ligand adsorption}},
url = {{http://dx.doi.org/10.1088/0953-8984/22/47/472002}},
doi = {{10.1088/0953-8984/22/47/472002}},
volume = {{22}},
year = {{2010}},
}