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Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]

Johnson, Magnus LU and Wendt, Ola LU (2011) In Inorganica Chimica Acta 367(1). p.222-224
Abstract
The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Nickel, Phosphine, Cyclometallation, Pincer ligands
in
Inorganica Chimica Acta
volume
367
issue
1
pages
222 - 224
publisher
Elsevier
external identifiers
  • wos:000286930000032
  • scopus:79551681273
ISSN
0020-1693
DOI
10.1016/j.ica.2010.12.007
language
English
LU publication?
yes
id
e2c1b6dd-c2ee-4308-b5ac-561e22cf28ca (old id 1872840)
date added to LUP
2011-04-18 11:17:02
date last changed
2017-01-01 06:17:46
@article{e2c1b6dd-c2ee-4308-b5ac-561e22cf28ca,
  abstract     = {The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.},
  author       = {Johnson, Magnus and Wendt, Ola},
  issn         = {0020-1693},
  keyword      = {Nickel,Phosphine,Cyclometallation,Pincer ligands},
  language     = {eng},
  number       = {1},
  pages        = {222--224},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]},
  url          = {http://dx.doi.org/10.1016/j.ica.2010.12.007},
  volume       = {367},
  year         = {2011},
}