Advanced

Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster

Jalilian, Ehsan and Lidin, Sven LU (2011) In Solid State Sciences 13(4). p.768-772
Abstract
Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Copper(I) iodide cluster, Structure
in
Solid State Sciences
volume
13
issue
4
pages
768 - 772
publisher
Editions scientifiques Elsevier
external identifiers
  • wos:000289965900014
  • scopus:79953057620
ISSN
1873-3085
DOI
10.1016/j.solidstatesciences.2010.03.019
language
English
LU publication?
yes
id
a8f4e0a2-a713-48c3-b2f9-3c968eda43d2 (old id 1987068)
date added to LUP
2011-06-29 09:49:54
date last changed
2017-01-01 03:17:46
@article{a8f4e0a2-a713-48c3-b2f9-3c968eda43d2,
  abstract     = {Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.},
  author       = {Jalilian, Ehsan and Lidin, Sven},
  issn         = {1873-3085},
  keyword      = {Copper(I) iodide cluster,Structure},
  language     = {eng},
  number       = {4},
  pages        = {768--772},
  publisher    = {Editions scientifiques Elsevier},
  series       = {Solid State Sciences},
  title        = {Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster},
  url          = {http://dx.doi.org/10.1016/j.solidstatesciences.2010.03.019},
  volume       = {13},
  year         = {2011},
}