The new nickel tellurite chloride compound Ni15Te12O34Cl10 - synthesis, crystal structure and magnetic properties
(2013) In Dalton Transactions 42(5). p.1394-1399- Abstract
- A new nickel tellurite oxohalide, Ni15Te12O34Cl10, has been prepared by chemical vapour transport reactions and the crystal structure was determined by single-crystal X-ray diffraction. The compound crystallizes in the triclinic space group P (1) over bar with the pseudomonoclinic cell parameters a = 10.3248(6) angstrom, b = 10.3249(6) angstrom, c = 11.6460(8) angstrom, alpha = 73.782(6)degrees, beta = 73.782(6)degrees, gamma = 63.51(2)degrees, Z = 1, R-1 = 0.0264. The Ni2+ ions have octahedral [NiO6] and [NiO4Cl2] coordinations, the Te4+ ions have one-sided [TeO3] and [TeO4] coordinations. The crystal structure can be described as consisting of nickel oxide ribbons extending along (001) that are connected by corner sharing [TeO3] and... (More)
- A new nickel tellurite oxohalide, Ni15Te12O34Cl10, has been prepared by chemical vapour transport reactions and the crystal structure was determined by single-crystal X-ray diffraction. The compound crystallizes in the triclinic space group P (1) over bar with the pseudomonoclinic cell parameters a = 10.3248(6) angstrom, b = 10.3249(6) angstrom, c = 11.6460(8) angstrom, alpha = 73.782(6)degrees, beta = 73.782(6)degrees, gamma = 63.51(2)degrees, Z = 1, R-1 = 0.0264. The Ni2+ ions have octahedral [NiO6] and [NiO4Cl2] coordinations, the Te4+ ions have one-sided [TeO3] and [TeO4] coordinations. The crystal structure can be described as consisting of nickel oxide ribbons extending along (001) that are connected by corner sharing [TeO3] and [TeO4] groups to build the open framework structure. The chlorine atoms and the Te-lone pairs are facing voids in the oxide framework. The new compound undergoes two successive antiferromagnetic ordering transitions at similar to 50 K and similar to 10 K. The Curie-Weiss temperature obtained from detailed evaluation of the high-temperature magnetic susceptibilities is positive indicating predominant ferromagnetic superexchange interactions between the Ni magnetic moments. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3595980
- author
- Zhang, Dong ; Johnsson, Mats ; Lidin, Sven LU and Kremer, Reinhard K.
- organization
- publishing date
- 2013
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Dalton Transactions
- volume
- 42
- issue
- 5
- pages
- 1394 - 1399
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000313616600013
- scopus:84872071257
- pmid:23135641
- ISSN
- 1477-9234
- DOI
- 10.1039/c2dt32158k
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- 198a3085-b0a0-4014-9501-4f79aec2e509 (old id 3595980)
- date added to LUP
- 2016-04-01 10:28:07
- date last changed
- 2022-02-25 02:05:16
@article{198a3085-b0a0-4014-9501-4f79aec2e509,
abstract = {{A new nickel tellurite oxohalide, Ni15Te12O34Cl10, has been prepared by chemical vapour transport reactions and the crystal structure was determined by single-crystal X-ray diffraction. The compound crystallizes in the triclinic space group P (1) over bar with the pseudomonoclinic cell parameters a = 10.3248(6) angstrom, b = 10.3249(6) angstrom, c = 11.6460(8) angstrom, alpha = 73.782(6)degrees, beta = 73.782(6)degrees, gamma = 63.51(2)degrees, Z = 1, R-1 = 0.0264. The Ni2+ ions have octahedral [NiO6] and [NiO4Cl2] coordinations, the Te4+ ions have one-sided [TeO3] and [TeO4] coordinations. The crystal structure can be described as consisting of nickel oxide ribbons extending along (001) that are connected by corner sharing [TeO3] and [TeO4] groups to build the open framework structure. The chlorine atoms and the Te-lone pairs are facing voids in the oxide framework. The new compound undergoes two successive antiferromagnetic ordering transitions at similar to 50 K and similar to 10 K. The Curie-Weiss temperature obtained from detailed evaluation of the high-temperature magnetic susceptibilities is positive indicating predominant ferromagnetic superexchange interactions between the Ni magnetic moments.}},
author = {{Zhang, Dong and Johnsson, Mats and Lidin, Sven and Kremer, Reinhard K.}},
issn = {{1477-9234}},
language = {{eng}},
number = {{5}},
pages = {{1394--1399}},
publisher = {{Royal Society of Chemistry}},
series = {{Dalton Transactions}},
title = {{The new nickel tellurite chloride compound Ni15Te12O34Cl10 - synthesis, crystal structure and magnetic properties}},
url = {{http://dx.doi.org/10.1039/c2dt32158k}},
doi = {{10.1039/c2dt32158k}},
volume = {{42}},
year = {{2013}},
}