Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

Luminescence properties of monoclinic Cu4I4(Piperidine)(4)

Jalilian, Ehsan ; Liao, Rong-Zhen ; Himo, Fahmi and Lidin, Sven LU (2011) In Materials Research Bulletin 46(8). p.1192-1196
Abstract
A new modification of Cu(4)I(4)Pip(4) has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu(4)I(4)Pip(4), the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission. (C) 2011 Elsevier Ltd. All rights reserved.
Please use this url to cite or link to this publication:
author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Luminescence
in
Materials Research Bulletin
volume
46
issue
8
pages
1192 - 1196
publisher
Elsevier
external identifiers
  • wos:000292722900007
  • scopus:79958129576
ISSN
0025-5408
DOI
10.1016/j.materresbull.2011.04.012
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
id
b8d388bf-0847-499a-a0f8-8277f0af72d8 (old id 2093955)
date added to LUP
2016-04-01 15:04:18
date last changed
2021-05-25 03:51:38
@article{b8d388bf-0847-499a-a0f8-8277f0af72d8,
  abstract     = {A new modification of Cu(4)I(4)Pip(4) has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu(4)I(4)Pip(4), the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission. (C) 2011 Elsevier Ltd. All rights reserved.},
  author       = {Jalilian, Ehsan and Liao, Rong-Zhen and Himo, Fahmi and Lidin, Sven},
  issn         = {0025-5408},
  language     = {eng},
  number       = {8},
  pages        = {1192--1196},
  publisher    = {Elsevier},
  series       = {Materials Research Bulletin},
  title        = {Luminescence properties of monoclinic Cu4I4(Piperidine)(4)},
  url          = {http://dx.doi.org/10.1016/j.materresbull.2011.04.012},
  doi          = {10.1016/j.materresbull.2011.04.012},
  volume       = {46},
  year         = {2011},
}