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Luminescence properties of monoclinic Cu4I4(Piperidine)(4)

Jalilian, Ehsan; Liao, Rong-Zhen; Himo, Fahmi and Lidin, Sven LU (2011) In Materials Research Bulletin 46(8). p.1192-1196
Abstract
A new modification of Cu(4)I(4)Pip(4) has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu(4)I(4)Pip(4), the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission. (C) 2011 Elsevier Ltd. All rights reserved.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Luminescence
in
Materials Research Bulletin
volume
46
issue
8
pages
1192 - 1196
publisher
Elsevier
external identifiers
  • wos:000292722900007
  • scopus:79958129576
ISSN
0025-5408
DOI
10.1016/j.materresbull.2011.04.012
language
English
LU publication?
yes
id
b8d388bf-0847-499a-a0f8-8277f0af72d8 (old id 2093955)
date added to LUP
2011-08-25 12:08:33
date last changed
2017-01-01 06:35:05
@article{b8d388bf-0847-499a-a0f8-8277f0af72d8,
  abstract     = {A new modification of Cu(4)I(4)Pip(4) has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu(4)I(4)Pip(4), the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission. (C) 2011 Elsevier Ltd. All rights reserved.},
  author       = {Jalilian, Ehsan and Liao, Rong-Zhen and Himo, Fahmi and Lidin, Sven},
  issn         = {0025-5408},
  keyword      = {Luminescence},
  language     = {eng},
  number       = {8},
  pages        = {1192--1196},
  publisher    = {Elsevier},
  series       = {Materials Research Bulletin},
  title        = {Luminescence properties of monoclinic Cu4I4(Piperidine)(4)},
  url          = {http://dx.doi.org/10.1016/j.materresbull.2011.04.012},
  volume       = {46},
  year         = {2011},
}