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Evidence for the formation of an intermediate complex in the direct metalation of tetra(4-bromophenyl)-porphyrin on the Cu(111) surface

Doyle, Catherine M. ; Krasnikov, Sergey A. ; Sergeeva, Natalia N. ; Preobrajenski, Alexei LU ; Vinogradov, Nikolay LU orcid ; Sergeeva, Yulia N. ; Senge, Mathias O. and Cafolla, Attilio A. (2011) In Chemical Communications 47(44). p.12134-12136
Abstract
A strong molecule-surface interaction between free-base-tetra(4-bromophenyl)-porphyrin and Cu(111) results in a distortion of both the molecule and the underlying copper surface in the vicinity of the molecule. This in turn leads to the formation of an intermediate complex due to bonding between the iminic nitrogens and surface copper atoms.
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author
; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Communications
volume
47
issue
44
pages
12134 - 12136
publisher
Royal Society of Chemistry
external identifiers
  • wos:000296342800029
  • scopus:80155196007
  • pmid:21993371
ISSN
1364-548X
DOI
10.1039/c1cc15241f
language
English
LU publication?
yes
id
b6b7b91d-67c7-430c-a271-d68d75681695 (old id 2207916)
date added to LUP
2016-04-01 11:12:14
date last changed
2021-08-18 05:10:52
@article{b6b7b91d-67c7-430c-a271-d68d75681695,
  abstract     = {A strong molecule-surface interaction between free-base-tetra(4-bromophenyl)-porphyrin and Cu(111) results in a distortion of both the molecule and the underlying copper surface in the vicinity of the molecule. This in turn leads to the formation of an intermediate complex due to bonding between the iminic nitrogens and surface copper atoms.},
  author       = {Doyle, Catherine M. and Krasnikov, Sergey A. and Sergeeva, Natalia N. and Preobrajenski, Alexei and Vinogradov, Nikolay and Sergeeva, Yulia N. and Senge, Mathias O. and Cafolla, Attilio A.},
  issn         = {1364-548X},
  language     = {eng},
  number       = {44},
  pages        = {12134--12136},
  publisher    = {Royal Society of Chemistry},
  series       = {Chemical Communications},
  title        = {Evidence for the formation of an intermediate complex in the direct metalation of tetra(4-bromophenyl)-porphyrin on the Cu(111) surface},
  url          = {http://dx.doi.org/10.1039/c1cc15241f},
  doi          = {10.1039/c1cc15241f},
  volume       = {47},
  year         = {2011},
}